Perfeziona i miei risultati

Collection spécifique

Lingua

Université de Fribourg

Coupling of electronic and nuclear motion in a negative ion resonance: Experimental and theoretical study of benzene

Allan, Michael ; Čurík, Roman ; Čársky, Petr

In: The Journal of Chemical Physics, 2019, vol. 151, no. 6, p. 064119

We present calculated and measured elastic and vibrational excitation cross sections in benzene with the objective to assess the reliability of the theoretical method and to shed more light on how the electronic motion of the incoming electron is coupled with the nuclear motion of the vibrations. The calculation employed the discrete momentum representation method which involves solving the...

Consortium of Swiss Academic Libraries

More Than Charged Base Loss — Revisiting the Fragmentation of Highly Charged Oligonucleotides

Nyakas, Adrien ; Eberle, Rahel ; Stucki, Silvan ; Schürch, Stefan

In: Journal of The American Society for Mass Spectrometry, 2014, vol. 25, no. 7, p. 1155-1166

Université de Fribourg

Hypersatellite x-ray decay of $3d$ hollow-$K$-shell atoms produced by heavy-ion impact

Maillard, Yves-Patrick ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Berset, Michel ; Mauron, Olivier ; Raboud, Pierre-Alexandre ; Kavčič, Matjaz ; Rzadkiewicz, J. ; Banaś, Dariusz ; Tökési, K.

In: Physical Review A, 2018, vol. 98, no. 1, p. 012705

We report on the radiative decay of double K-shell vacancy states produced in solid Ca, V, Fe, and Cu targets by impact with about 10 MeV/amu C and Ne ions. The resulting K hypersatellite x-ray emission spectra were measured by means of high- energy-resolution spectroscopy using a von Hamos bent crystal spectrometer. The experiment was carried out at the Philips variable energy cyclotron of...

Université de Fribourg

Dissociative electron attachment and electronic excitation in Fe(CO)5

Allan, Michael ; Lacko, M. ; Papp, P. ; Matejčík, Š. ; Zlatar, Matija ; Fabrikant, Ilya I. ; Kočišek, J. ; Fedor, Juraj

In: Physical Chemistry Chemical Physics, 2018, vol. 20, no. 17, p. 11692–11701

In a combined experimental and theoretical study we characterize dissociative electron attachment (DEA) to, and electronically excited states of, Fe(CO)5. Both are relevant for electron-induced degradation of Fe(CO)5. The strongest DEA channel is cleavage of one metal–ligand bond that leads to production of Fe(CO)4−. High- resolution spectra of Fe(CO)4− reveal fine structures at the...

Consortium of Swiss Academic Libraries

Conformation-Specific Spectroscopy of Peptide Fragment Ions in a Low-Temperature Ion Trap

Wassermann, Tobias ; Boyarkin, Oleg ; Paizs, Béla ; Rizzo, Thomas

In: Journal of The American Society for Mass Spectrometry, 2012, vol. 23, no. 6, p. 1029-1045