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    Université de Fribourg

    Low-energy electron attachment to the dichlorodifluoromethane (CCl₂F₂) molecule

    Graupner, K. ; Haughey, S. A. ; Field, T. A. ; Mayhew, C. A. ; Hoffmann, T. H. ; May, Olivier ; Fedor, Juraj ; Allan, Michael ; Fabrikant, Ilya I. ; Illenberger, E. ; Braun, M. ; Ruf, M.-W. ; Hotop, Hartmut

    In: The Journal of Physical Chemistry A, 2010, vol. 114, no. 3, p. 1474–1484

    Results from a joint experimental study of electron attachment to dichlorodifluoromethane (CCl₂F₂) molecules in the gas phase are reported. In a high resolution electron beam experiment involving two versions of the laser photoelectron attachment method, the relative cross section for formation of the dominant anion Cl⁻ was measured over the energy range 0.001−1.8 eV at the gas...

    Université de Fribourg

    Resonance structure in electron–N₂ scattering around 11.5 eV: high-resolution measurements, ab initio calculations and line shape analyses

    Hoffmann, T. H. ; Allan, Michael ; Franz, K. ; Ruf, M.-W. ; Hotop, Hartmut ; Sauter, G. ; Meyer, W.

    In: Journal of Physics B, 2009, vol. 42, no. 21, p. 215202

    Using two different experimental setups with energy widths of about 6 and 13 meV, we obtained significantly improved results for the energy dependence of angle-differential (10°–180°) elastic and vibrationally inelastic cross sections for electron scattering from N₂ molecules in the energy range around the narrow N⁻₂(R²Σ⁺g) resonance. The energy location and the natural...

    Université de Fribourg

    Resonance structure in low-energy electron scattering from OCS

    Hoffmann, T. H. ; Hotop, H. ; Allan, Michael

    In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2008, vol. 41, no. 9, p. 195202

    Energy-dependent absolute angle-differential cross sections (θ = 135°) for elastic and vibrationally inelastic electron scattering from OCS molecules have been investigated at high resolution (13 meV). The elastic cross section, reported over the range E= 0.06–20 eV, exhibits a deep Ramsauer–Townsend minimum near 0.55 eV and the π*(1.2 eV) and σ*(3.8 eV) resonances known from...