Perfeziona i miei risultati

Conserved functions of ether lipids and sphingolipids in the early secretory pathway

Jiménez-Rojo, Noemi ; Leonetti, Manuel D. ; Zoni, Valeria ; Colom, Adai ; Feng, Suihan ; Iyengar, Namrata R. ; Matile, Stefan ; Roux, Aurélien ; Vanni, Stefano ; Weissman, Jonathan S. ; Riezman, Howard

In: Current Biology, 2020, vol. 30, no. 19, p. 3775-3787.e7

Sphingolipids play important roles in physiology and cell biology, but a systematic examination of their functions is lacking. We performed a genome-wide CRISPRi screen in sphingolipid-depleted human cells and identified hypersensitive mutants in genes of membrane trafficking and lipid biosynthesis, including ether lipid synthesis. Systematic lipidomic analysis showed a coordinate regulation...

Telechelics based on catalytic alternating ring-opening metathesis polymerization

Pal, Subhajit ; Alizadeh, Mahshid ; Kilbinger, Andreas F. M.

In: ACS Macro Letters, 2019, vol. 8, no. 10, p. 1396–1401

We describe a protocol to synthesize alternating telechelic ROMP copolymers of 7- oxa-norbornene derivatives and cycloalkenes under catalytic conditions. These copolymers were synthesized using Grubbs’ second-generation catalyst. The sterically less hindered backbone double bonds of the resulting alternating copolymers facilitate the chain transfer (secondary metathesis) reactions. In the ...

Functional end groups in living ring-opening metathesis polymerization

Kilbinger, Andreas

In: Synlett, 2019, vol. 30, no. 18, p. 2051–2057

Over the last two decades many synthetic methods have been reported to selectively introduce a number of different functional groups at the chain end of a living ring- opening metathesis polymer. In this personal account, I would like to focus on a few such methods developed in my research group over the last several years and how these led to the discovery of catalytic living ring-opening...

Structure and Magnetic Properties of the Radical Cation Salt of a TTF-based NiII Complex

Liu, S-X ; Ambrus, C. ; Dolder, S. ; Neels, A. ; Labat, G. ; Decurtins, S.

In: Journal of Low Temperature Physics, 2006, vol. 142, no. 3-4, p. 461-464

Application of quantum-chemical methods including density functional theory for the interpretation of isotropic hyperfine data. The example of azulenebenzoquinone

Gescheidt, G. ; Barbosa, F. ; Daub, J. ; Bindl, J.

In: Applied Magnetic Resonance, 1997, vol. 13, no. 3-4, p. 405-413

Open Quantum Systems Coupled to Time-Dependent Classical Environments

Osmanov, Maksym ; Öttinger, Hans

In: International Journal of Thermophysics, 2013, vol. 34, no. 7, p. 1255-1264

Rac-(2R*,3R*)- S -Ethyl-4-Chloro-3-Hydroxy-2-Phenylbuthanethioate and Rac-(2R*,3R*)- S -Ethyl-2-Phenyl-3-(tosyloxy)buthanethioate: Dichotomy of the Stereoselectivity of the Mukaiyama Reaction

Vallat, Oliver ; Buciumas, Ana-Maria ; Neier, Reinhard ; Stoeckli-Evans, Helen

In: Journal of Chemical Crystallography, 2010, vol. 40, no. 1, p. 10-14

Small Mass Implies Uniqueness of Gibbs States of a Quantum Crystal

Albeverio, Sergio ; Kondratiev, Yuri ; Kozitsky, Yuri ; Röckner, Michael

In: Communications in Mathematical Physics, 2003, vol. 241, no. 1, p. 69-90

Quantitative time-resolved EPR CIDEP study of the photodecomposition of trans -azocumene in solution

Savitsky, A. ; Paul, H.

In: Applied Magnetic Resonance, 1997, vol. 12, no. 4, p. 449-464

Heterotelechelic polymers by ring‐opening metathesis and regioselective chain transfer

Yasir, Peng Liu, Mohammad ; Ruggi, Albert ; Kilbinger, Andreas F. M.

In: Angewandte Chemie International Edition, 2018, vol. 57, no. 4, p. 914–917

Heterotelechelic polymers were synthesized by a kinetic telechelic ring-opening metathesis polymerization method relying on the regioselective cross-metathesis of the propagating Grubbs’ first-generation catalyst with cinnamyl alcohol derivatives. This procedure allowed the synthesis of hetero-bis-end-functional polymers in a one- pot setup. The molecular weight of the polymers could be...