Perfeziona i miei risultati

Colloidal Stability and Toxicity of Gold Nanoparticles and Gold Chloride on Chlamydomonas reinhardtii

Behra, Renata ; Wagner, Bettina ; Sgier, Linn ; Kistler, David

In: Aquatic Geochemistry, 2015, vol. 21, no. 2-4, p. 331-342

Comparison of sp-ICP-MS and MDG-ICP-MS for the determination of particle number concentration

Gschwind, Sabrina ; Aja Montes, Maria ; Günther, Detlef

In: Analytical and Bioanalytical Chemistry, 2015, vol. 407, no. 14, p. 4035-4044

Effects of an iron-based fuel-borne catalyst and a diesel particle filter on exhaust toxicity in lung cells in vitro

Steiner, Sandro ; Czerwinski, Jan ; Comte, Pierre ; Heeb, Norbert ; Mayer, Andreas ; Petri-Fink, Alke ; Rothen-Rutishauser, Barbara

In: Analytical and Bioanalytical Chemistry, 2015, vol. 407, no. 20, p. 5977-5986

Synthesis and reactivity of the 17 e- complex [Re(II)Br4(CO)2]2 : A convenient entry into rhenium(II) chemistry

Zobi, Fabio ; Kromer, Lukas ; Spingler, Bernhard ; Alberto, Roger

In: Inorganic Chemistry, 2009, vol. 48, no. 18, p. 8965-8970

The reduction of (Et(4)N)[Re(III)Br(4)(CO)(2)] (1) by 0.5 equiv of tetrakis- dimethylaminoethylene in acetonitrile yields directly the air-stable, 17-electron Re(II) synthon (Et(4)N)(2)[Re(II)Br(4)(CO)(2)] (2) in nearly quantitative yield. The versatility of 2 as a synthon for Re(II) chemistry was demonstrated by substitution reactions of [Re(II)Br(4)(CO)(2)](2-) with different mono-, bi-,...

Aerobically stable and substitutionally labile α-diimine rhenium dicarbonyl complexes

Schindler, Kevin ; Crochet, Aurélien ; Zobi, Fabio

In: RSC Advances, 2021, vol. 11, p. 7511-7520

New synthetic routes to aerobically stable and substitutionally labile α-diimine rhenium(I) dicarbonyl complexes are described. The molecules are prepared in high yield from the cis–cis–trans-[Re(CO)2(tBu2bpy)Br2]− anion (2, where tBu2bpy is 4,4′- di-tert-butyl-2,2′-bipyridine), which can be isolated from the one electron reduction of the corresponding 17-electron complex (1)....

Stereospecific hydrogenolysis of benzylic alcohols over Pd/C

Harvey, Freya M. ; Bochet, Christian G.

In: The Journal of Organic Chemistry, 2020, vol. 85, no. 11, p. 7611–7619

Hydrogenolysis of tertiary benzylic alcohols on palladium on carbon (Pd/C) generally proceeds with inversion of configuration. However, little is known about the hydrogenolysis mechanism of primary and secondary benzylic alcohols. Literature precedents suggest that these substrates may interact differently with the catalyst. To study the mechanism, we synthesized a pair of deuterated...

Indirect solvent assisted tautomerism in 4-substituted phthalimide 2-hydroxy-Schiff bases

Yordanov, Dancho ; Deneva, Vera ; Georgiev, Anton ; Crochet, Aurélien ; Fromm, Katharina M. ; Antonova, Liudmil

In: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2020, vol. 237, p. 118416

The paper presents the synthesis and characterization of two 4-substituted phthalimide 2-hydroxy-Schiff bases containing salicylic (4) and 2-hydroxy-1-naphthyl (5) moieties. The structural differences of 2-hydroxyaryl substituents, resulting in different enol/keto tautomeric behaviour, depending on the solvent environment were studied by absorption UV–Vis spectroscopy. Compound 5 is...

State of the Art and Perspectives in the "Molecular Approach” Towards Well-Defined Heterogeneous Catalysts

Conley, Matthew ; Copéret, Christophe

In: Topics in Catalysis, 2014, vol. 57, no. 10-13, p. 843-851

Formation Mechanism of Alkyl Nitrites, Valuable Intermediates in C1-Upgrading Chemistry and Oxidation Processes

Hermans, Ive ; Teles, Joaquim ; Dehn, Richard ; Brüggemann, Till-Christian ; Send, Robert ; Plessow, Philipp

In: Topics in Catalysis, 2014, vol. 57, no. 14-16, p. 1256-1264

Dissolution and transformation of cerium oxide nanoparticles in plant growth media

Schwabe, Franziska ; Schulin, Rainer ; Rupper, Patrick ; Rotzetter, Aline ; Stark, Wendelin ; Nowack, Bernd

In: Journal of Nanoparticle Research, 2014, vol. 16, no. 10, p. 1-11