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    Université de Fribourg

    Transient anions of cis- and trans-cyclooctene studied by electron-impact spectroscopy

    Regeta, Khrystyna ; Nagarka, Amit ; Kilbinger, Andreas F. M. ; Allan, Michael

    In: Physical Chemistry Chemical Physics, 2015, vol. 17, no. 6, p. 4696–4700

    The effect which deformation of the double bond in trans-cyclooctene (TCO), compared to cis-cyclooctene (CCO), has on its negative ion – and indirectly on the π* virtual orbital – was studied by electron-impact spectroscopy. Differential elastic and vibrational excitation cross sections were measured at a scattering angle of θ = 135°. The vertical attachment energy (VAE) derived from the...