In: Molecular Physics, 2013, p. -
The electronic structure of TEMPO (2,2,6,6-Tetramethylpiperidine-N-oxyl) and its cation and anion were studied experimentally using the electron spectroscopy techniques, dissociative electron attachment (DEA) spectroscopy, electron energy-loss spectroscopy, measurement of elastic and vibrational excitation (VE) cross sections and HeI photoelectron spectroscopy. The experiments were supplemented...
|
In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2007, vol. 40, no. 1, p. 101-109
Electron-induced chemistry—dissociative electron attachment (DEA)—was studied for phenyl azide. The major fragment corresponded to the loss of N₂ and formation of the phenylnitrene anion. This process has an onset already at zero kinetic energy of the incident electron and is interpreted as proceeding via the A″π* electronic ground state of the phenyl azide anion. Other fragments,...
|