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Consortium of Swiss Academic Libraries

More Than Charged Base Loss — Revisiting the Fragmentation of Highly Charged Oligonucleotides

Nyakas, Adrien ; Eberle, Rahel ; Stucki, Silvan ; Schürch, Stefan

In: Journal of The American Society for Mass Spectrometry, 2014, vol. 25, no. 7, p. 1155-1166

Université de Fribourg

Dissociative electron attachment and electronic excitation in Fe(CO)5

Allan, Michael ; Lacko, M. ; Papp, P. ; Matejčík, Š. ; Zlatar, Matija ; Fabrikant, Ilya I. ; Kočišek, J. ; Fedor, Juraj

In: Physical Chemistry Chemical Physics, 2018, vol. 20, no. 17, p. 11692–11701

In a combined experimental and theoretical study we characterize dissociative electron attachment (DEA) to, and electronically excited states of, Fe(CO)5. Both are relevant for electron-induced degradation of Fe(CO)5. The strongest DEA channel is cleavage of one metal–ligand bond that leads to production of Fe(CO)4−. High- resolution spectra of Fe(CO)4− reveal fine structures at the...

Consortium of Swiss Academic Libraries

Conformation-Specific Spectroscopy of Peptide Fragment Ions in a Low-Temperature Ion Trap

Wassermann, Tobias ; Boyarkin, Oleg ; Paizs, Béla ; Rizzo, Thomas

In: Journal of The American Society for Mass Spectrometry, 2012, vol. 23, no. 6, p. 1029-1045

Consortium of Swiss Academic Libraries

New aspects of the fragmentation mechanisms of unmodified and methylphosphonate-modified oligonucleotides

Monn, Selina ; Schürch, Stefan

In: Journal of the American Society for Mass Spectrometry, 2007, vol. 18, no. 6, p. 984-990

Consortium of Swiss Academic Libraries

Gas-phase Dissociation of homo-DNA Oligonucleotides

Stucki, Silvan ; Désiron, Camille ; Nyakas, Adrien ; Marti, Simon ; Leumann, Christian ; Schürch, Stefan

In: Journal of The American Society for Mass Spectrometry, 2013, vol. 24, no. 12, p. 1997-2006