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Organization of spin- and redox-labile metal centers into Langmuir and Langmuir–Blodgett films

Gandolfi, Claudio ; Miyashita, Naoko ; Kurth, Dirk G. ; Martinho, Paulo N. ; Morgan, Grace G. ; Albrecht, Martin

In: Dalton Transactions, 2010, vol. 39, p. 4508-4516

New sal₂(trien) ligands that contain alkoxy substituents of various length in meta position of the phenolate entities were coordinated to electronically and magnetically active iron(III) and cobalt(III) centers. The electrochemical and spectroscopic properties of these amphiphilic complexes are virtually unaffected upon alteration of the alkoxy substituents, thus providing a system...