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    Université de Fribourg

    Generation of alkoxyl radicals and their applications for ß-scission reactions in bridged bicyclic systems

    Giraud, Anne ; Renaud, Philippe (Dir.) ; Cossy, Janine (Codir.)

    Thèse de doctorat : Université de Fribourg, 2000 ; no 1319.

    Due to their peculiar reactivity, alkoxyl radicals have unique characteristic properties, which make them powerful tools in modern organic chemistry. Among their typical transformations, β-scission reactions have retained our interest because of their potential in converting stereoselectively bridged bicyclic systems into a variety of useful synthetic intermediates. In this work, we describe our...