Université de Neuchâtel

Hydrogénation catalytique des calix[4]pyrolles pour l'obtention de nouveaux ligands : synthèses, structures, complexes de cuivre et de manganèse et leur application dans des processus d'oxydation catalytique

Blangy, Valeria ; Neier, Reinhard (Dir.)

Thèse de doctorat : Université de Neuchâtel, 2007 ; Th.2005.

The goal of this work of thesis was to develop a new effective manganese catalyst for oxidation processes with H2O2 as oxidant. The first part of this project was devoted to the synthesis of the starting materials, the meso-octaalkylporphyrinogenes, such as 84, 117-120. These compounds are easily accessible by condensation in acid medium between the pyrrole and various ketones. In the second...