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    Université de Fribourg

    On the role of the II(1/2g) state in spontaneous dissociation of krypton and xenon dimer ions

    Fedor, Juraj ; Echt, O. ; Głuch, K. ; Matt-Leubner, S. ; Scheier, P. ; Märk, T.D.

    In: Chemical Physics Letters, 2007, vol. 437, no. 4-6, p. 183-188

    We have measured kinetic-energy-release distributions (KERD) for spontaneous dissociation of electronically excited dimer ions of krypton and xenon, formed by electron impact ionization of neutral precursors. The data cannot be reconciled by decay of the strongly bound II(1/2u) state that successfully explains dissociation of and Ne₂⁺ and Ar₂⁺. Instead, the KERD is dominated by...