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Compartmentalization of alkaline-earth metals in salen-type Cu- and Ni-complexes in solution and in the solid state

Finelli, Alba ; Hérault, Nelly ; Crochet, Aurélien ; Fromm, Katharina M.

In: ACS Omega, 2019, vol. 4, no. 6, p. 10231–10242

The precise arrangement of metal ions in type and number by a ligand represents an important challenge in biology as well as in materials science. The preorganization of different metal ions such as alkaline-earth and transition-metal ions is of particular interest for the design of catalysts or precursors of oxides. This study is based on a Ω- shaped salen-derived ligand comprising N2O2 and...