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Synthesis, X-ray structure and in vitro cytotoxicity studies of Cu(I/II) complexes of thiosemicarbazone: special emphasis on their interactions with DNA

Saswati ; Chakraborty, Ayon ; Dash, Subhashree P. ; Panda, Alok K. ; Acharyya, Rama ; Biswas, Ashis ; Mukhopadhyay, Subhadip ; Bhutia, Sujit K. ; Crochet, Aurélien ; Patil, Yogesh P. ; Nethaji, M. ; Dinda, Rupam

In: Dalton Transactions, 2015, vol. 44, no. 13, p. 6140–6157

4-(p-X-phenyl)thiosemicarbazone of napthaldehyde {where X = Cl (HL¹) and X = Br (HL²)}, thiosemicarbazone of quinoline-2-carbaldehyde (HL³) and 4-(p-fluorophenyl)thiosemicarbazone of salicylaldehyde (H₂L⁴) and their copper(I) {[Cu(HL¹)(PPh₃)₂Br]·CH₃CN (1) and [Cu(HL²)(PPh₃)₂Cl]·DMSO (2)} and copper(II)...