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Université de Neuchâtel

Water-Soluble Arene Ruthenium Complexes Containing a trans-1,2-Diaminocyclohexane Ligand as Enantioselective Transfer Hydrogenation Catalysts in Aqueous Solution

Canivet, Jérôme ; Labat, Gael ; Stoeckli-Evans, Helen ; Süss-Fink, Georg

In: European Journal of Inorganic Chemistry, 2005, vol. 22, p. 4493 - 4500

The cationic chloro complexes [(arene)Ru(H2N∩NH2)Cl]+ (1: arene = C6H6; 2: arene = p-MeC6H4iPr; 3: arene = C6Me6) have been synthesised from the corresponding arene ruthenium dichloride dimers and enantiopure (R,R or S,S)...

Université de Neuchâtel

Water-Soluble Phenanthroline Complexes of Rhodium, Iridium and Ruthenium for the Regeneration of NADH in the Enzymatic Reduction of Ketones

Canivet, Jérôme ; Süss-Fink, Georg ; Štěpnička, Petr

In: European Journal of Inorganic Chemistry, 2007, vol. 30, p. 4736 - 4742

The nicotinamide coenzyme NADH, consumed in enantioselective reduction of ketones catalysed by alcohol dehydrogenases, needs to be regenerated in order to maintain enzymatic activity. We therefore studied the catalytic potential of the cationic complexes [(η5-C5Me5)Rh(N∩N)Cl]+ (1: N∩N = 1,10-phenanthroline; 2: N∩N =...