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    Université de Fribourg

    Influence of linear and branched perfluoroalkylated side chains on the π–π stacking behaviour of hexa-peri-hexabenzocoronene and thermotropic properties

    Alameddine, Bassam ; Aebischer, Olivier Frédéric ; Heinrich, Benoît ; Guillon, Daniel ; Donnio, Bertrand ; Jenny, Titus A.

    In: Supramolecular Chemistry, 2014, vol. 26, no. 2, p. 125–137

    The thermotropic properties and self-assembly of two different series of hexa-peri-hexabenzocoronenes (HBC) bearing either linear or branched perfluoroalkylated side chains, each with a wide range of alkyl spacer and perfluorinated tail lengths, have been studied. Correlations between thermogravimetric analysis, differential scanning calorimetry, polarised optical microscopy and small-angle X-ray...