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Université de Fribourg

Functional columnar liquid crystalline phases from ionic complexes of dendronized polymers and sulfate alkyl tails

Canilho, Nadia ; Kasëmi, Edis ; Schlüter, Dieter A. ; Ruokolainen, Janne ; Mezzenga, Raffaele

In: Macromolecular Symposia, 2008, vol. 270, no. 1, p. 58 - 64

We describe how cationic dendronized polymers of generations 1, and 2 and anionic monoalkyl tails can be combined by supramolecular ionic complexation into comb-like liquid crystalline polymers. The final structures in bulk of these supramolecular complexes were studied by differential scanning calorimetry (DSC), cross-polarized optical microscopy (CPOM), small angle x-rays scattering (SAXS) and...