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Université de Fribourg

Perturbations to astronomical observations at the European Southern Observatory's very large telescope site in Paranal, Chile: analyses of climatological causes

Beniston, Martin ; Casals, Paula ; Sarazin, Marc S.

In: Theoretical and Applied Climatology, 2002, vol. 73(3-4), p. 133-150

A study has been conducted to assess the reasons for a significant decrease in the astronomic observing period since the Very Large Telescope of ESO (the European Southern Observatory) went into operation in 1998. Following a multi-year monitoring of meteorological parameters at the site of the ESO telescope in Paranal (northern Chile), the optimal climatic conditions observed there prior to the...

Université de Fribourg

Nonlinearities, feedbacks and critical thresholds within the earth's climate system

Rial, José A. ; Pielke, Roger A. ; Beniston, Martin ; Claussen, Martin ; Canadell, Josep ; Cox, Peter ; Held, Hermann ; Noblet-Ducoudré, Nathalie de ; Prinn, Ronald ; Reynolds, James F. ; Salas, José D.

In: Climatic Change, 2004, vol. 65, p. 11

The Earth's climate system is highly nonlinear: inputs and outputs are not proportional, change is often episodic and abrupt, rather than slow and gradual, and multiple equilibria are the norm. While this is widely accepted, there is a relatively poor understanding of the different types of nonlinearities, how they manifest under various conditions, and whether they reflect a climate system...

Université de Fribourg

Protonation behaviour of chiral tetradentate polypyridines derived from α-Pinene

Düggeli, Mathias ; Christen, Tobias ; Zelewsky, Alexander von

In: Chemistry - A European Journal, 2005, vol. 11, p. 185-194

Detailed protonation experiments of the [5,6]-pinenebipyridine molecule and the unsubstituted [4,5]- and [5,6]-CHIRAGEN[0] ligands in various solvents indicate a variety of structures of the protonated species. UV-visible and NMR measurements (including ¹⁵N chemical shifts) show the transition from trans to cis conformation of [5,6]-pinenebipyridine upon protonation. The...

Université de Fribourg

Diastereoselective synthesis of coordination compounds: a chiral tripodal ligand based on bipyridine units and its ruthenium(II) and iron(II) complexes

Hamann, Christine ; Zelewsky, Alexander von ; Neels, Antonia ; Stoeckli-Evans, Helen

In: Dalton Transactions, 2004, vol. 3, p. 402-406

The enantiomerically pure chiral tris-chelating ligand (+)-(7S,10R)-L(L) comprising three 4,5-pinenobipyridine subunits connected through a mesityl spacer has been synthesized. Complexes of L with RuII and FeII have been prepared and characterised. NMR spectroscopy indicates that...

Université de Fribourg

Elastic scattering, vibrational excitation, and attachment in low-energy electron-SF₆ scattering: Experiment and effective range theory

Fabrikant, Ilya I. ; Hotop, Hartmut ; Allan, Michael

In: Physical Review A, 2005, vol. 71, p. 022712-22721

Cross sections at low energies for vibrationally elastic and inelastic scattering, as well as electron attachment to SF₆, have been calculated using a multichannel effective range theory (ERT) with complex boundary conditions. The most active vibrational modes, the totally symmetric mode ν1 and the infrared active mode ν3, have been included in the calculation. The ERT parameters were fitted...

Université de Fribourg

Decay channels in the dissociative electron attachment to NO

Allan, Michael

In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2004, vol. 37, p. L359-L363

Kinetic energy spectra of O⁻ from dissociative electron attachment (DEA) to NO were measured at 7.6, 8.0, 9.0 and 10.0 eV electron energy using a spectrometer with hemispherical energy selectors for both the incident electrons and the resulting ions. The measurements were performed at 10°, 30°, 90° and 135°. The capacity of the spectrometer to detect both slow and fast ions was verified and...

Université de Fribourg

Evidences of winter ascending air circulation throughout talus slopes and rock glaciers situated in the lower belt of alpine discontinuous permafrost (Swiss Alps)

Delaloye, Reynald ; Lambiel, Christophe

In: Norwegian Journal of Geography

The winter ascending circulation of air throughout an accumulation of coarse slope sediments (the so-called chimney effect) facilitates the cooling of the ground and even the occurrence of permafrost in the lower part of a deposit. Simultaneously, any freezing is unlikely to occur in the upper part. The chimney effect has been reported to date mainly for cold and sometimes perennially frozen...

Université de Fribourg

Electron collisions with NO: Elastic scattering, vibrational excitation, and ²Πi1/2 ⇌ ²Π3/2 transitions

Allan, Michael

In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2005, vol. 38, p. 603

Absolute differential elastic and vibrational excitation cross sections have been measured for NO at 135° with resolution of the ²Π1/2 and ²Π3/2 spin-orbit components of the ground electronic term. The electronic fine structure excitation is dominated by the ³Σ⁻ and the ¹Δ resonances of NO⁻, the nonresonant contribution is very small. The cross section is very large, it has about the...

Université de Fribourg

Paradoxes in the logistic equation?

Gabriel, Jean-Pierre ; Saucy, Francis ; Bersier, Louis-Félix

In: Ecological Modelling

Levins and Ginzburg raised two paradoxes concerning the logistic equation of population growth. None of them received a satisfactory answer within the frame of the original equation. Here, we propose solutions to both paradoxes.