In: JBIC Journal of Biological Inorganic Chemistry, 2015, vol. 20, no. 1, p. 49-59
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In: Inorganic Chemistry, 2009, vol. 48, no. 18, p. 8965-8970
The reduction of (Et(4)N)[Re(III)Br(4)(CO)(2)] (1) by 0.5 equiv of tetrakis- dimethylaminoethylene in acetonitrile yields directly the air-stable, 17-electron Re(II) synthon (Et(4)N)(2)[Re(II)Br(4)(CO)(2)] (2) in nearly quantitative yield. The versatility of 2 as a synthon for Re(II) chemistry was demonstrated by substitution reactions of [Re(II)Br(4)(CO)(2)](2-) with different mono-, bi-,...
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In: Reaction Kinetics and Catalysis Letters, 2009, vol. 98, no. 2, p. 205-213
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In: JBIC Journal of Biological Inorganic Chemistry, 2009, vol. 14, no. 5, p. 693-701
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In: JBIC Journal of Biological Inorganic Chemistry, 2012, vol. 17, no. 6, p. 951-960
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In: JBIC Journal of Biological Inorganic Chemistry, 2009, vol. 14, no. 1, p. 101-109
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In: JBIC Journal of Biological Inorganic Chemistry, 2010, vol. 15, no. 5, p. 677-688
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In: JBIC Journal of Biological Inorganic Chemistry, 2012, vol. 17, no. 7, p. 1053-1062
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In: European Journal of Inorganic Chemistry, 2011, vol. 2011, no. 18, p. 2863–2868
N-Heterocyclic carbene (NHC) ruthenium complexes consisting of different donor substituents attached to the NHC ligand efficiently catalyse the transfer hydrogenation of ketones and of activated olefins in α,β-unsaturated ketones to give saturated alcohols. The most active catalyst precursor contains a tethered olefin as a hemilabile donor site. This complex also converts nitriles and,...
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