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Université de Fribourg

Synthesis of Hexa-peri-hexobenzocoronenes Carrying Linear or Branched Perfluoroalkylated Side Chains

Aebischer, Olivier F. ; Muñoz, David T. ; Tondo, Patrick ; Débieux, Jean-Luc ; Jenny, Titus A.

In: Synthesis, 2010, vol. 7, p. 1123-1140

Substituted disc-shaped perfluoroalkylated hexa-peri-hexabenzocoronenes (HBC), known to self-assemble into conducting ordered architectures, were synthesized and characterized. A systematic variation of the linear or branched perfluoroalkylated side chains was performed in order to screen the influence of the lateral chain on their one-dimensional self-aggregation.