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    Université de Fribourg

    Magnetic properties of silica coated spindle-type hematite particles

    Reufer, Mathias ; Dietsch, Hervé ; Gasser, Urs ; Grobéty, Bernard ; Hirt, A. M. ; Malik, Vivek Kumar ; Schurtenberger, Peter

    In: Journal of Physics: Condensed Matter, 2011, vol. 23, no. 6, p. 065102

    Magnetic properties of particles are generally determined from randomly oriented ensembles and the influence of the particle orientation on the magnetic response is neglected. Here, we report on the magnetic characterization of anisotropic spindle- type hematite particles. The easy axis of magnetization is within the basal plane of hematite, which is oriented perpendicular to the spindle axis....

    Université de Fribourg

    Morphology and orientational behavior of silica-coated spindle-type hematite particles in a magnetic field probed by small-angle x-ray scattering

    Reufer, Mathias ; Dietsch, Hervé ; Gasser, Urs ; Hirt, Ann ; Menzel, Andreas ; Schurtenberger, Peter

    In: Journal of Physical Chemistry B, 2010, vol. 114, no. 14, p. 4763-4769

    Form factor and magnetic properties of silica-coated spindle-type hematite nanoparticles are determined from SAXS measurements with applied magnetic field and magnetometry measurements. The particle size, polydispersity and porosity are determined using a core−shell model for the form factor. The particles are found to align with their long axis perpendicular to the applied field. The...