In: Journal of Biomolecular NMR, 2015, vol. 63, no. 1, p. 21-37
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In: Molecules, 2020, vol. 25, no. 2, p. 298
Two novel pinene-type ligands have been synthesized and their tautomeric and self- associating behavior studied in solution and in the solid state. The first ligand, an acetylated derivative of 5,6-pinene-bipyridine, displays keto-enol tautomerism in solution. This tautomeric equilibrium was studied by NMR and UV-Vis spectroscopy in various solvents, and the results were compared with the ones...
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In: Journal of Biomolecular NMR, 2013, vol. 55, no. 4, p. 339-353
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In: Journal of Biomolecular NMR, 2007, vol. 39, no. 3, p. 229-238
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In: Journal of Biomolecular NMR, 2004, vol. 30, no. 4, p. 407-422
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In: Hyperfine Interactions, 2009, vol. 193, no. 1-3, p. 39-45
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In: Dalton Transactions, 2018, vol. 47, no. 14, p. 4785–4789
A versatile synthetic methodology to access the first family of chiral verdazyl N,N′- chelate ligands is described and exemplified by N,N′-dimethyl-, N,N′-di-isopropyl- and N,N′-diphenyl oxoverdazyls bearing two isomers of the pinene-pyridine functional group. Their physical properties were probed by X-band EPR spectroscopy, cyclic voltammetry and DFT calculations. Preliminary...
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In: Inorganica Chimica Acta, 2018, vol. 475, p. 200–206
Two new chiral bis-bidentate, C2-symmetrical ligands belonging to the Chiragen family have been synthesised and characterised. They are designed for polynuclear self-assemblies since the two (−)-5,6-pinenebipyridines units are connected by bridges whose length and rigidity avoids the coordination of the bipyridine moieties to the same metal centre. The ligand L1 with a 1,4-dimethylene...
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In: Quarterly Reviews of Biophysics, 1977, vol. 10, no. 3, p. 353-418
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In: Glycobiology, 2003, vol. 13, no. 6, p. 435-443
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