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    Université de Fribourg

    Accounting for effective interactions among charged microgels

    Aguirre-Manzo, L. A. ; Ledesma-Motolinía, Mónica ; Rojas-Ochoa, Luis Fernando ; Trappe, Véronique ; Callejas-Fernández, J. ; Haro-Pérez, Catalina ; González-Mozuelos, P.

    In: Physical Review E, 2019, vol. 100, no. 3, p. 032602

    We introduce a theoretical approach to describe structural correlations among charged permeable spheres at finite particle concentrations. This theory explicitly accounts for correlations among microions and between microions and macroions and allows for the proposal of an effective interaction among macroions that successfully captures structural correlations observed in poly- N -isopropyl...

    Université de Fribourg

    Impact of volume transition on the net charge of poly-$N$-isopropyl acrylamide microgels

    Braibanti, Marco ; Haro-Pérez, Catalina ; Quesada-Pérez, M. ; Rojas-Ochoa, Luis Fernando ; Trappe, Véronique

    In: Physical Review E, 2016, vol. 94, no. 3, p. 032601

    We explore the electrostatic properties of poly-N-isopropyl acrylamide microgels in dilute, quasi-de-ionized dispersions and show that the apparent net charge of these thermosensitive microgels is an increasing function of their size, the size being conveniently varied by temperature. Our experimental results obtained in a combination of light scattering, conductivity, and mobility...