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Université de Neuchâtel

Malonylation/Decarbalkoxylation of Furan Derivatives as Key Steps for the Preparation of Nonactic Acid Derivatives. Part I [1]

Simone, Jean-Mary ; Loiseau, François ; Carcache, David ; Bobal, Pavel ; Jeanneret-Gris, Julie ; Neier, Reinhard

In: Monatshefte für Chemie / Chemical Monthly, 2007, vol. 138, no. 2, p. 131-139

A malonylation/decarbalkoxylation sequence from 2-substituted furans was investigated in view of developing a scalable synthesis of hydrophobic nonactic acid analogues.

Université de Neuchâtel

Macrocyclisation of 2-(5-(2-hydroxyethyl)furan-2-yl)acetic acid model compounds of nonactic acid

Eng, Carine ; Simone, Jean-Mary ; Hartenbach, Akane ; Loiseau, François ; Neier, Reinhard

In: Monatshefte für Chemie / Chemical Monthly, 2009, vol. 140, no. 3, p. 349-354

The macrocyclisation of hydroxyethylfuranyl acetic acid and of dehydrogenated model compounds of nonactic acid was investigated to develop a facile synthesis of nonactin analogues. By applying the Yamagushi macrocyclisation to our ω-hydroxyacids, we were able to isolate a mixture of di-, tri-, tetra- and pentameric macrocycles.

Université de Neuchâtel

Malonylation/Decarbalkoxylation of Furan Derivatives as Key Steps for the Preparation of Nonactic Acid Derivatives. Part II [1]

Simone, Jean-Mary ; Loiseau, François ; Carcache, David ; Bobal, Pavel ; Jeanneret-Gris, Julie ; Neier, Reinhard

In: Monatshefte für Chemie / Chemical Monthly, 2007, vol. 138, no. 2, p. 141-147

A malonylation/decarbalkoxylation sequence from 2-substituted furans was investigated in view of developing a scalable synthesis of hydrophobic nonactic acid analogues.