In: Angewandte Chemie International Edition, 2020, vol. 59, no. 32, p. 13597-13601
Using a one-step synthetic route for block copolymers avoids the repeated addition of monomers to the polymerization mixture, which can easily lead to contamination and, therefore, to the unwanted termination of chain growth. For this purpose, monomers (M1–M5) with different steric hindrances and different propagation rates are explored. Copolymerization of M1 (propagating rapidly) with M2...
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In: Polymers, 2018, vol. 10, no. 11, p. 1188
In this study, polyaspartamide-based hydrogels were synthesized by boron-catechol coordination followed by incorporation of AgNPs into the materials. Free catechol moieties were exploited to produce AgNPs. TEM analyses displayed AgNPs of less than 20 nm in diameter and with minimum aggregation, attesting the role of hydrogels to act as an efficient template for the production of dispersed...
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In: Journal of Materials Science: Materials in Medicine, 2004, vol. 15, no. 4, p. 519-522
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In: The European Physical Journal E, 2007, vol. 24, no. 4, p. 379-384
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In: Biomechanics and Modeling in Mechanobiology, 2013, vol. 12, no. 2, p. 243-248
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In: Rheologica Acta, 2007, vol. 46, no. 8, p. 1109-1119
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In: Rheologica Acta, 2009, vol. 48, no. 7, p. 769-778
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In: Journal of Materials Science: Materials in Medicine, 2010, vol. 21, no. 3, p. 999-1004
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In: Macromolecular Chemistry and Physics, 2017/218/22/n/a-n/a
In this work, the influence of carbon nanotubes (CNTs) on the self-assembly of nanocomposite materials made of cylinder-forming polystyrene-block-poly(ethylene- butylene)-block-polystyrene (SEBS) is studied. CNTs are modified with polystyrene (PS) brushes by surface-initiated atom transfer radical polymerization to facilitate both their dispersion and the orientation of neighboring PS domains...
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In: Macromolecules, 2017, vol. 50, no. 23, p. 9307–9314
Herein we report the facile synthesis of an amphiphilic rod–coil block copolymer obtained by the coupling of an amine-terminated poly(dimethylpropylamine norbornene imide) (PDMAPNI) and a pentafluorophenol ester-terminated poly(dimethoxybenzyl p-aminobenzoate) (PAram). Postpolymerization amide N- deprotection of the block copolymer yielded a strongly aggregating water-soluble rod– coil...
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