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Catalytic Hydrogenation of meso-Octamethylporphyrinogen (Calix[4]pyrrole)

Journot, Guillaume ; Letondor, Christophe ; Neier, Reinhard ; Stoeckli-Evans, Helen ; Savoia, Diego ; Gualandi, Andrea

In: Chemistry - A European Journal, 2010, vol. 16, no. 4, p. 4224-4230

Hydrogenation of meso-octamethylporphyrinogen (calix[4]pyrrole) with a number of heterogeneous catalysts under different experimental conditions has been investigated. GC-MS analyses of the reaction mixtures showed the formation of one to four products in low to moderate yields: three of them were diastereoisomers of the product derived from half-hydrogenation of the substrate, and displayed...

Synthesis, Structure, and Complexation Properties of Partially and Completely Reduced meso-Octamethylporphyrinogens (Calix[4]pyrroles)

Blangy, Valeria ; Heiss, Christoph ; Khlebnikov, Vsevolod ; Letondor, Christophe ; Stoeckli-Evans, Helen ; Neier, Reinhard

In: Angewandte Chemie International Edition, 2009, vol. 48, no. 9, p. 1688-1691