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Tuning the solubility of hepta(p-benzamide)s via the monomer sequence

Seyler, Helga ; Kilbinger, Andreas

In: Tetrahedron Letters, 2012, p. -

The automated synthesis of hepta(p-benzamide) hetero sequences on solid support using a modified peptide synthesizer is reported. The oligomers are synthesized from 4-aminobenzoic acid and 4-amino-2-(hexyloxy)benzoic acid, the latter carrying a solubilizing hexyl side chain. It is known from previous studies that both the unsubstituted hepta(p-benzamide) and the fully hexyloxy-substituted...