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Université de Fribourg

Photonic properties of strongly correlated colloidal liquids

Rojas-Ochoa, Luis Fernando ; Mendez-Alcaraz, J. M. ; Sáenz, J. J. ; Schurtenberger, Peter ; Scheffold, Frank

In: Physical Review Letters, 2004, vol. 93, p. 073903-73906

The optical and structural properties of dense colloidal suspensions in the presence of long-range electrostatic repulsion are determined from both light and small-angle neutron scattering experiments. Short-range structural order induces an enhancement of the scattering strength while at the same time the total transmission shows strong wavelength dependence, reminiscent of a photonic crystal....

Université de Fribourg

Scattering functions of semidilute solutions of polymers in a good solvent

Pedersen, Jan Skov ; Schurtenberger, Peter

In: Journal of Polymer Science Part B: Polymer Physics, 2004, vol. 42, p. 3081-3094

Expressions for analyzing small-angle scattering data from semidilute solutions of polymers in a good solvent over a broad range of scattering vectors are examined. Three different scattering function expressions are derived from Monte Carlo simulations. The expressions are similar to those of polymer reference interaction site models, with a scattering-vector-dependent direct correlation...

Université de Fribourg

Optical imaging of the spatiotemporal dynamics of cerebral blood flow and oxidative metabolism in the rat barrel cortex

Weber, B. ; Burger, C. ; Wyss, M. T. ; Schulthess, G. K. von ; Scheffold, Frank ; Buck, Alfred

In: European Journal of Neuroscience, 2004, vol. 20, p. 2664-2670

Oxidative metabolism and cerebral blood flow (CBF) are two of the most important measures in neuroimaging. However, results from concurrent imaging of the two with high spatial and temporal resolution have never been published. We used flavoprotein autofluorescence (AF) and laser speckle imaging (LSI) in the anaesthetized rat to map oxidative metabolism and CBF in response to single vibrissa...

Université de Fribourg

Heterogeneous dynamics of coarsening systems

Mayer, P. ; Bissig, Hugo ; Berthier, L. ; Cipelletti, Luca ; Garrahan, J. P. ; Sollich, P. ; Trappe, Véronique

In: Physical Review Letters, 2004, vol. 93, p. 11570-11573

We show by means of experiments, theory, and simulations that the slow dynamics of coarsening systems displays dynamic heterogeneity similar to that observed in glass-forming systems. We measure dynamic heterogeneity via novel multipoint functions which quantify the emergence of dynamic, as opposed to static, correlations of fluctuations. Experiments are performed on a coarsening foam using...

Université de Fribourg

Burckhardtsche Bestimmung der Raumgruppen II

Strebel, Ralph

In: Elemente der Mathematik, 2004, vol. 59, p. 1-18

Université de Fribourg

Burckhardtsche Bestimmung der Raumgruppen I

Strebel, Ralph

In: Elemente der Mathematik, 2003, vol. 58, p. 141-155

Université de Fribourg

Depolarization of backscattered linear lypolarized ligh

Rojas-Ochoa, Luis Fernando ; Lacoste, David ; Lenke, Ralf ; Schurtenberger, Peter ; Scheffold, Frank

In: Journal of the Optical Society of America: A, 2004, vol. 21, p. 1799-1804

We formulate a quantitative description of backscattered linearly polarized light with an extended photon diffusion formalism taking explicitly into account the scattering anisotropy parameter g of the medium. From diffusing wave spectroscopy measurements, the characteristic depolarization length for linearly polarized light, lp, is deduced. We investigate the dependence of this length on the...

Université de Fribourg

Colloidal gels—low-density disordered solid-like states

Trappe, Veronique ; Sandkühler, Peter

In: Current Opinion in Colloid & Interface Science, 2004, vol. 8, p. 494-500

The analogies between colloidal glasses and gels have stimulated an increased effort in recent years to unify the description of the transitions to these disordered solid-like states within a single conceptual framework. Mode coupling theory, which successfully describes the hard sphere colloidal glass transition, has been extended to describe the effect of weak attractions at large volume...

Université de Fribourg

Tracer microrheology of γ-dodecalactone induced gelation of aqueous starch dispersions

Heinemann, Cornelia ; Cardinaux, Frédéric ; Scheffold, Frank ; Schurtenberger, Peter ; Escher, Felix ; Conde-Petit, Béatrice

In: Carbohydrate Polymers, 2004, vol. 55, p. 155-161

We have studied the rheological properties of the natural biopolymer system starch in the presence of the gelation inducing flavor compound γ-dodecalactone. From optical microrheology, based on the multiple scattering of laser light (DWS), we deduce the frequency-dependent moduli G(ω) and G″(ω) of the gelling sample over the full frequency range. Our measurements demonstrate the inherent...

Université de Fribourg

Characterization of the pores in hydrous ferric oxide aggregates formed by freezing and thawing

Hofmann, Annette ; Pelletier, Manuel ; Michot, Laurent ; Stradner, Anna ; Schurtenberger, Peter ; Kretzschmar, Ruben

In: Journal of Colloid and Interface Science, 2004, vol. 271, p. 163-173

Hydrous ferric oxides (HFO) are efficient sorbents for inorganic and organic pollutants and therefore have great potentials in environmental science and engineering applications. Freezing and thawing of HFO suspensions leads to the formation of dense HFO aggregates. It facilitates the handling and increases the drying rate of HFO. In this study, we used a combination of pycnometry, gas adsorption...