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    Université de Fribourg

    Bimetallic metal organic frameworks with precisely positioned metal centers for efficient H2 storage

    Kim, Daeok ; Song, Kyung Seob ; Buyukcakir, Onur ; Yildirim, Taner ; Coskun, Ali

    In: Chemical Communications, 2018, vol. 54, no. 86, p. 12218–12221

    We demonstrated that the ratio and position of two different metal ions, Pd and Cu, can be precisely controlled within MOFs through predesigned metal clusters. These MOF structures incorporating Pd–Cu paddle wheel units were synthesised simply by reacting Pd–Cu acetate metal clusters and tritopic organic linkers at room temperature. Pd–Cu open metal sites were found to be uniformly...