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Haute école de gestion de Genève

Le cobalt durable, une réalité ?

Maddalena, Nicola ; Mach, Antoine (Dir.)

Mémoire de bachelor : Haute école de gestion de Genève, 2021 ; TDEE 470.

Le cobalt est une ressource qui connait une augmentation importante de sa demande, augmentation due à son utilisation toujours plus fréquente dans les nouvelles technologies. Cette demande en constante croissance entraine une course à l’extraction qui est sujette à de nombreux défis, tant sur le plan éthique que durable. De son approvisionnement jusqu’à sa transformation et son...

Consortium of Swiss Academic Libraries

Life cycle assessment study of a field emission display television device

Hischier, Roland

In: The International Journal of Life Cycle Assessment, 2015, vol. 20, no. 1, p. 61-73

Université de Fribourg

Nitrogen-doped carbons with hierarchical porosity via chemical blowing towards long-lived metal-free catalysts for acetylene hydrochlorination

Kaiser, Selina K. ; Song, Kyung Seob ; Mitchell, Sharon ; Coskun, Ali ; Pérez‐Ramírez, Javier

In: ChemCatChem, 2020, vol. 12, no. 7, p. 1922-1925

Porous nitrogen‐doped carbons (NCs) are sustainable alternatives to the toxic mercury‐based acetylene hydrochlorination catalysts applied in the manufacture of polyvinyl chloride. However, the application of NCs as metal‐free catalysts is hampered by their insufficient durability under industrially relevant process conditions. In particular, pore blockage leads to accelerated...

Université de Fribourg

Highly elastic polyrotaxane binders for mechanically stable lithium hosts in lithium‐metal batteries

Yoo, Dong‐Joo ; Elabd, Ahmed ; Choi, Sunghun ; Cho, Yunshik ; Kim, Jaemin ; Lee, Seung Jong ; Choi, Seung Ho ; Kwon, Tae‐woo ; Char, Kookheon ; Kim, Ki Jae ; Coskun, Ali ; Choi, Jang Wook

In: Advanced Materials, 2019, vol. 31, no. 29, p. 1901645

Despite their unparalleled theoretical capacity, lithium‐metal anodes suffer from well‐ known indiscriminate dendrite growth and parasitic surface reactions. Conductive scaffolds with lithium uptake capacity are recently highlighted as promising lithium hosts, and carbon nanotubes (CNTs) are an ideal candidate for this purpose because of their capability of percolating a conductive...

Université de Fribourg

Revealing the role of epithelial mechanics and macrophage clearance during pulmonary epithelial injury recovery in the presence of carbon nanotubes

Septiadi, Dedy ; Abdussalam, Wildan ; Rodriguez‐Lorenzo, Laura ; Spuch‐Calvar, Miguel ; Bourquin, Joël ; Petri‐Fink, Alke ; Rothen‐Rutishauser, Barbara

In: Advanced Materials, 2018, vol. 30, no. 52, p. 1806181

Wound healing assays are extensively used to study tissue repair mechanisms; they are typically performed by means of physical (i.e., mechanical, electrical, or optical) detachment of the cells in order to create an open space in which live cells can lodge. Herein, an advanced system based on extensive photobleaching‐induced apoptosis; providing a powerful tool to understand the repair...

Université de Fribourg

Novel iron tweezers complexes for hydrogenation and polymerization of olefins

Mafua, Roger ; Jenny, Titus A. (Dir.)

Thèse de doctorat : Université de Fribourg, 2006 ; no. 1503.

L’utilisation des complexes organométalliques comme catalyseurs est devenu un domaine très important de la chimie des matériaux. Cependant et malgré ce développement, les catalyseurs à base de fer(II) sont peu employés dans la polymérisation d’oléfines. Un de rares catalyseur utilisé dans ce contexte est le complexe tridenté diimine pyridine développé par Gibson et Brookhart....

Université de Fribourg

Heptacoordinate Co(II) catalyst for light-driven hydrogen production in fully aqueous medium

Lucarini, Fiorella ; Ruggi, Albert

In: CHIMIA International Journal for Chemistry, 2018, vol. 72, no. 4, p. 203–206

Photocatalytic hydrogen production is an appealing way to store solar energy as chemical fuel. The most studied molecular catalysts for H2 production are based on earth-abundant metals such as Ni, Co and Fe. Efforts have been recently focused on the design of Co complexes with distorted octahedral geometries induced by tetra- or pentapyridyl ligands. We synthesized a new Co(II) complex based...