In: JBIC Journal of Biological Inorganic Chemistry, 2015, vol. 20, no. 1, p. 49-59
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In: Journal of Nanoparticle Research, 2015, vol. 17, no. 10, p. 1-13
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In: Materials Chemistry Frontiers, 2020, vol. 4, no. 9, p. 2791–2796
The second-generation Hoveyda–Grubbs (HG2) catalyst, which has a small initiation to propagation rate ratio (ki/kp) in ring-opening metathesis polymerization (ROMP), was successfully used in a recently developed catalytic living ROMP. This proved that slow-initiating catalysts can enable ROMP in a living fashion to produce polymers with narrow dispersity and controlled molecular weight. The...
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In: Catalysis Letters, 2014, vol. 144, no. 3, p. 373-379
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In: Nature Chemistry, 2019, vol. 11, no. 5, p. 488–494
In a conventional living ring-opening metathesis polymerization (ROMP), an equal number of ruthenium complexes to the number of polymer chains synthesized are required. This can lead to high loadings of ruthenium complexes when aiming for shorter polymers. Here, a reversible chain-transfer agent was used to produce living ROMP polymers from norbornene derivatives using catalytic amounts of...
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Thèse de doctorat : Université de Fribourg, 2006 ; no. 1503.
L’utilisation des complexes organométalliques comme catalyseurs est devenu un domaine très important de la chimie des matériaux. Cependant et malgré ce développement, les catalyseurs à base de fer(II) sont peu employés dans la polymérisation d’oléfines. Un de rares catalyseur utilisé dans ce contexte est le complexe tridenté diimine pyridine développé par Gibson et Brookhart....
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In: CHIMIA International Journal for Chemistry, 2018, vol. 72, no. 4, p. 203–206
Photocatalytic hydrogen production is an appealing way to store solar energy as chemical fuel. The most studied molecular catalysts for H2 production are based on earth-abundant metals such as Ni, Co and Fe. Efforts have been recently focused on the design of Co complexes with distorted octahedral geometries induced by tetra- or pentapyridyl ligands. We synthesized a new Co(II) complex based...
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In: Journal of Cluster Science, 2007, vol. 18, no. 1, p. 87-95
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In: Catalysis Letters, 2003, vol. 88, no. 3-4, p. 105-113
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In: Kinetics and Catalysis, 2012, vol. 53, no. 2, p. 253-261
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