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Université de Fribourg

One-step ring opening metathesis block-like copolymers and their compositional analysis by a novel retardation technique

Yasir, Mohammad ; Liu, Peng ; Markwart, Jens C. ; Suraeva, Oksana ; Wurm, Frederik R. ; Smart, Jansie ; Lattuada, Marco ; Kilbinger, Andreas F. M.

In: Angewandte Chemie International Edition, 2020, vol. 59, no. 32, p. 13597-13601

Using a one-step synthetic route for block copolymers avoids the repeated addition of monomers to the polymerization mixture, which can easily lead to contamination and, therefore, to the unwanted termination of chain growth. For this purpose, monomers (M1–M5) with different steric hindrances and different propagation rates are explored. Copolymerization of M1 (propagating rapidly) with M2...

Université de Fribourg

Structural behavior of cylindrical polystyrene-block-poly(ethylene-butylene)-block-polystyrene (SEBS) triblock copolymer containing MWCNTs: on the influence of nanoparticle surface modification

Hasanabadi, Noushin ; Nazockdast, Hossein ; Gajewska, Bernadetta ; Balog, Sandor ; Gunkel, Ilja ; Bruns, Nico ; Lattuada, Marco

In: Macromolecular Chemistry and Physics, 2017/218/22/n/a-n/a

In this work, the influence of carbon nanotubes (CNTs) on the self-assembly of nanocomposite materials made of cylinder-forming polystyrene-block-poly(ethylene- butylene)-block-polystyrene (SEBS) is studied. CNTs are modified with polystyrene (PS) brushes by surface-initiated atom transfer radical polymerization to facilitate both their dispersion and the orientation of neighboring PS domains...

Université de Fribourg

Losses and depolarization of ultracold neutrons on neutron guide and storage materials

Bondar, V. ; Chesnevskaya, S. ; Daum, M. ; Franke, B. ; Geltenbort, P. ; Göltl, L. ; Gutsmiedl, E. ; Karch, J. ; Kasprzak, Malgorzata ; Kessler, G. ; Kirch, K. ; Koch, Hans-Christian ; Kraft, Andreas ; Lauer, Thorsten ; Lauss, B. ; Pierre, E. ; Pignol, G. ; Reggiani, D. ; Schmidt-Wellenburg, P. ; Sobolev, Yuri ; Zechlau, T. ; Zsigmond, G.

In: Physical Review C, 2017, vol. 96, no. 3, p. 035205

At Institut Laue-Langevin (ILL) and Paul Scherrer Institute (PSI), we have measured the losses and depolarization probabilities of ultracold neutrons on various materials: (i) nickel-molybdenum alloys with weight percentages of 82/18, 85/15, 88/12, 91/9, and 94/6 and natural nickel Ni100, (ii) nickel-vanadium NiV93/7, (iii) copper, and (iv) deuterated polystyrene (dPS). For the different...

Université de Fribourg

Rheological characterization of nanostructured material based on Polystyrene-b-poly(ethylene-butylene)-b-polystyrene (SEBS) block copolymer: Effect of block copolymer composition and nanoparticle geometry

Hasanabadi, Noushin ; Nazockdast, Hossein ; Balog, Sandor ; Lattuada, Marco

In: Composites Science and Technology, 2017, vol. 149, no. Supplement C, p. 192–206

Block copolymer (BCP) nanocomposite systems are of broad interest; however, reports on the role of nanoparticles on microphase separation behavior are rare. The goal of present study is to investigate the preparation of composite nanostructured materials containing Multi-Walled Carbon Nanotubes (MWCNTs) or graphene nanoplates. BCP nanocomposites based on the linear triblock copolymer, ...