In: Scientific Reports, 2014, vol. 4, p. -
The enthalpically favoured hydration of hydrophobic entities, termed hydrophobic hydration, impacts the phase behaviour of numerous amphiphiles in water. Here, we show experimental evidence that hydrophobic hydration is strongly determined by the mean energetics of the aqueous medium. We investigate the aggregation and collapse of an amphiphilic polymer, poly-N-isopropyl acrylamide (PNiPAM), in...
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In: Journal of Rheology, 2017, vol. 61, no. 4, p. 817–831
We explore the dynamical and mechanical characteristics of an evolving gel in diffusing wave spectroscopy (DWS) and rheometry, aiming to assess how the gel evolution impacts the creep response of the system. Our gel is formed by inducing the aggregation of thermosensitive colloids by a variation in temperature. We find experimental evidence that the long time evolution of this gel is due to...
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