Université de Fribourg

Structural analysis of conformational flexibility in (aqua)(propanediamine-N,N '-diacetato-N-propionato)chromium(III) dihydrate. Crystal structure of cis-polar, trans(H₂O,O⁵)-[Cr(1,3-pddap)(H₂O)]·2H₂O

Grubišić, Sonja ; Gruden-Pavlović, Maja ; Niketić, Svetozar R. ; Sakagami-Yoshida, Narumi ; Kaizaki, Sumio

In: Journal of Coordination Chemistry, 2007, vol. 61, no. 8, p. 851 - 863

The quinquedentate complex trans(H₂O,O⁵)-[Cr(1,3-pddap)(H₂O)] · 2H₂O (where 1,3-pddap is the 1,3-propanediamine-N,N '-diacetate-N-3-propionate ion) was prepared and its structure established by X-ray diffraction method. It crystallizes in the orthorhombic space group Pna2₁, a = 17.290(2), b = 10.821(2), c = 7.872(1) Å, Z =...