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Kinetics of ion transport through supramolecular channels in single crystals

Assouma, Cyrille D. ; Crochet, Aurélien ; Chérémond, Yvens ; Giese, Bernd ; Fromm, Katharina M.

In: Angewandte Chemie International Edition, 2013, vol. 52, no. 17, p. 4682–4685

Single-crystal to single-crystal transformations are possible by ion-exchange and transport reactions through supramolecular channels that are composed of crown ether molecules and use trihalide ions as scaffolds. Kinetic measurements of ion transport at different temperatures provide activation energy data and show that a very fast.

Di-Benzo-18-Crown-6 and its Derivatives as Ligands in the Search for Ion Channels

Fromm, Katharina M. ; Bergougnant, Rémi D. ; Robin, Adeline Y.

In: Zeitschrift für anorganische und allgemeine Chemie, 2006, vol. 632, no. 5, p. 828 - 836