In: Dalton Transactions, 2013, vol. 42, no. 19, p. 6909–6921
The syntheses of H₂-phbpz, [Cu₂(phbpz)]·2DEF·MeOH (CFA-2) and [Ag₂(phbpz)] (CFA-3) (H₂-phbpz = 3,3′,5,5′-tetraphenyl-1H,1′H-4,4′-bipyrazole) compounds and their crystal structures are described. The Cu(I) containing metal–organic framework CFA-2 crystallizes in the tetragonal crystal system, within space...
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In: CrystEngComm, 2012, p. -
A new series of ligands in which nicotinic acid was linked to different monomethyloligoethers and their corresponding silver complexes were prepared. The crystal structures of the silver compounds were investigated to determine the effect of increasing flexibility of the ligands on coordination to the metal ion and crystal packing. We observed the formation of one-dimensional coordination...
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In: Zeitschrift für anorganische und allgemeine Chemie, 2011, vol. 637, no. 12, p. 1871–1879
Reaction of commercially available tetraethylene glycol with different alkaline earth metal halides affords tetraethylene glycol complexes with different coordination numbers at the metal ion and structural features; depending on the ionic radius of the metal ion, one or two ligand molecules will be coordinated to the metal ion. In this article we will first present complexes with...
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In: Journal of Coordination Chemistry, 2010, vol. 63, no. 18, p. 3175-3186
A 3-D metal-organic coordination polymer based on pyrazine-2,3-dicarboxylic acid (pzdcH₂) formulated as {[Mn(pzdc)(H₂O)₂] · 2H₂O}n (1), was obtained by the treatment of MnCl₂ · 6H₂O with pzdcH₂, 8-hydroxy quinoline (8-HQ), and 2-amino-4-methyl pyridine (ampy). In this study, we describe the synthesis, elemental analysis, IR spectroscopy, TG analysis, and...
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In: CHIMIA International Journal for Chemistry, 2010, vol. 64, no. 5, p. 299-320
Heterometallic oxides are used as materials in many applications, e.g. from ferroelectrics to superconductors. Making these compounds usually requires high temperatures and long reaction times. Molecular precursors may contribute to render their processing shorter and accessible at lower temperatures, thus cheaper in energy and time. In this review article, different approaches toward oxide...
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In: Inorganic Chemistry, 2009, vol. 48, no. 22, p. 10535–10547
The multitopic ligand O,O′-bisnicotinic acid tetraethylene glycol, L, was designed for the coordination of two distinct types of metal ions. In this work, we describe how the O-donor part of L is used to coordinate to alkaline earth metal ions and that the N-donor atoms of L bind to group 11 elements. This makes L a suitable ligand for the combination of both metal...
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