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Two new organotin(IV)-phosphoryl complexes: crystal structure and Hirshfeld surface analysis

Pourayoubi, Mehrdad ; Saneei, Anahid ; Dušek, Michal ; Rostami, Soobiyeh Alemi ; Crochet, Aurélien ; Kučeraková, Monika

In: Journal of the Iranian Chemical Society, 2015, vol. 12, no. 12, p. 2093–2103

Hirshfeld surfaces and two-dimensional fingerprint plots are used to visualize and analyse intermolecular interactions in two new organotin(IV)-phosphoryl complexes: [Sn(CH₃)₂[OP(O)(OCH₃)₂]₂]n (I) and {[(4-CH₃)C₆H₄NH][C₅H₉(4-CH₃)N]₂P(O)}Sn(CH₃)₂Cl₂ (II). In (I), the asymmetric unit is composed of the Sn(CH₃)₂[OP(O)(OCH₃)₂]₂ segment bonded to the...