Université de Fribourg

Population-balance description of shear-induced clustering, gelation and suspension viscosity in sheared DLVO colloids

Lattuada, Marco ; Zaccone, Alessio ; Wu, Hua ; Morbidelli, Massimo

In: Soft Matter, 2016, vol. 12, no. 24, p. 5313–5324

Application of shear flow to charge-stabilized aqueous colloidal suspensions is ubiquitous in industrial applications and as a means to achieve controlled field-induced assembly of nanoparticles. Yet, applying shear flow to a charge-stabilized colloidal suspension, which is initially monodisperse and in quasi-equilibrium leads to non-trivial clustering phenomena (and sometimes to a gelation...

Université de Fribourg

Unexpected Decoupling of Stretching and Bending Modes in Protein Gels

Gibaud, Thomas ; Zaccone, Alessio ; Gado, Emanuela Del ; Trappe, Véronique ; Schurtenberger, Peter

In: Physical Review Letters, 2013, vol. 110, no. 5, p. 058303

We show that gels formed by arrested spinodal decomposition of protein solutions exhibit elastic properties in two distinct frequency domains, both elastic moduli exhibiting a remarkably strong dependence on volume fraction. Considering the large difference between the protein size and the characteristic length of the network we model the gels as porous media and show that the high and low...

Université de Fribourg

Quantifying the reversible association of thermosensitive nanoparticles

Zaccone, Alessio ; Crassous, Jérôme J. ; Béri, Benjamin ; Ballauff, Matthias

In: Physics Review Letters, 2011, vol. 107, no. 16, p. 168303

Under many conditions, biomolecules and nanoparticles associate by means of attractive bonds, due to hydrophobic attraction. Extracting the microscopic association or dissociation rates from experimental data is complicated by the dissociation events and by the sensitivity of the binding force to temperature (T). Here we introduce a theoretical model that combined with light-scattering...