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Université de Fribourg

Film-forming polymers containing in the main-chain dibenzo crown ethers with aliphatic (C₁₀−C₁₆), aliphatic−aromatic, or oxyindole spacers

Zolotukhin, Mikhail G. ; Hernández, María del Carmen G. ; Lopez, Ana Maria ; Fomina, Loudmila ; Cedillo, Gerardo ; Nogales, Aurora ; Ezquerra, Tiberio ; Rueda, Daniel ; Colquhoun, Howard M. ; Fromm, Katharina M. ; Ruiz-Treviño, Alberto ; Ree, Moonhor

In: Macromolecules, 2006, vol. 39, no. 14, p. 4696–4703

Novel, linear, soluble, high-molecular-weight, film-forming polymers and copolymers in which main-chain crown ether units alternate with aliphatic (C₁₀−C₁₆) units have been obtained for the first time from aromatic electrophilic substitution reactions of crown ethers by aliphatic dicarboxylic acids followed by reduction of the carbonyl groups. The crown ether unit is dibenzo-18-crown-6,...

Université de Fribourg

Di-Benzo-18-Crown-6 and its Derivatives as Ligands in the Search for Ion Channels

Fromm, Katharina M. ; Bergougnant, Rémi D. ; Robin, Adeline Y.

In: Zeitschrift für anorganische und allgemeine Chemie, 2006, vol. 632, no. 5, p. 828 - 836

Université de Fribourg

On the coordination behaviour of NO₃⁻ in coordination compounds with Ag⁺Part 1. Solubility effect on the formation of coordination polymer networks between AgNO₃ and L(L= ethanediyl bis(isonicotinate) as a function of solvent

Robin, Adeline Y. ; Sagué, Jorge L. ; Fromm, Katharina M.

In: CrystEngComm, 2006, vol. 8, p. 403-416

The influence of the solubility of AgNO₃ in three solvent systems is studied for the reaction between AgNO₃ and the ligand L(= ethanediyl bis(isonicotinate)). Three solid state structures are obtained, differing in the relative ratio Ag : L in the first case, and in polymorphism in the second. The Ag–O(NO₃⁻) distance correlates strongly with the solubility of AgNO₃ in...

Université de Fribourg

Revision of the planktonic foraminifera Pseudothalmanninella klausi (LEHMANN, 1966) and Globotruncanella semsalensis (CORMINBOEUF, 1961) and first scanning electron microscope (SEM) images of the holotypes

Spezzaferri, Silvia ; Caron, Michèle

In: Revue de Paléobiologie, 2008, vol. 27, no. 1, p. 81-88

The planktonic foraminifera Rotalipora klausi Lehmann, 1966 and Globotruncana? semsalensis Corminboeuf, 1961, were figuredonly by drawings and the specimens were never made publicly available, although deposited in the collections of the Departmentof Geosciences, Fribourg, Switzerland. We present here for the first time their Scanning Electron Microscope documentation andcomparison with the...

Université de Fribourg

Sédimentologie et paléontologie des paléoenvironnements côtiers rupéliens de la Molasse marine rhénane dans le Jura suisse

Picot, Laurent ; Becker, Damien ; Cavin, Lionel ; Pirkenseer, Claudius ; Lapaire, Frédéric ; Rauber, Gaëtan ; Hochuli, Peter A. ; Spezzaferri, Silvia ; Berger, Jean-Pierre

In: Swiss Journal of Geosciences, 2008, vol. 101, no. 2, p. 483-513

Les dépôts oligocènes marins, situés dans la partie distale du bassin molassique suisse et dans le prolongement sud du fossé rhénan, sont constitués par les groupes stratigraphiques suivants: les Conglomérats de Porrentruy, le Septarienton et le Meeressand. Cette série sédimentaire a fait l’objet d’études stratigraphiques, sédimentologiques et paléontologiques détaillées. Trois...