Université de Fribourg

Cis- and trans-9,10-di(1H-imidazol-1-yl)-anthracene based coordination polymers of ZnII and CdII: synthesis, crystal structures and luminescence properties

Vasylevskyi, Serhii I. ; Regeta, Khrystyna ; Ruggi, Albert ; Petoud, Stéphane ; Piguet, Claude ; Fromm, Katharina M.

In: Dalton Transactions, 2018, vol. 47, no. 2, p. 596–607

New functional coordination polymers based on the semi-flexible 9,10-di(1H-imidazol- 1-yl)-anthracene ligand (L) with ZnII and CdII, namely {[Zn(μ2-L)2] (ClO4)2·m(MeOH)·n(DCM)}n (1), {[Zn(μ2-L)2](BF4)2·m(MeOH)·n(DCM)}n (2), {[Zn(μ2-L)2(p-Tos)2]·m(DCM)·n(MeOH)}n (3), {[Cd(μ2-L)2(p-Tos)2]·m(DCM)}n (4) {[Cd(μ2-L)2(p-Tos)2]·m(MeOH)·n(Dioxane)}n (5) and {[Zn(μ2-...