In: Sustainable Energy & Fuels, 2020, vol. 4, no. 2, p. 589–599
H2 evolution catalyzed by a heptacoordinate complex under both electro- (1) and photo-chemical (2) conditions is analyzed in detail in order to gain insights into the mechanism of the processes. The complex shows high catalytic activity for hydrogen production in acetonitrile, in the presence of trifluoroacetic acid and triethylammonium tetrafluoroborate as proton sources. Foot-of-the-wave...
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In: Polyhedron, 2019, vol. 173, p. 114112
The reactions between equimolar amounts of CuX2 (X = NO3− and CF3SO3−) and two aromatic nitrogen-containing heterocycles differing in the position of nitrogen atoms, 1,7- and 4,7-phenanthroline (1,7- and 4,7-phen), were performed in ethanol/methanol at room temperature. When CuX2 salts were mixed with 4,7-phen, two copper(II) complexes, [Cu(NO3)2(4,7-Hphen)2](NO3)2 (1) and...
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In: Physical Review B, 2019, vol. 99, no. 23, p. 235133
Nonlocal order parameters in space-time are proposed to characterize the unconventional orbital-selective conducting state in fulleride superconductors, called the Jahn-Teller metal. In previous works, it has been argued that this state can be interpreted as a spontaneous orbital-selective Mott state, in which the electrons in two of the three t1u molecular orbitals are localized, while those...
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In: Journal of the Serbian Chemical Society, 2019, vol. 84, no. 7, p. 689–699
New polynuclear silver(I) complexes, [Ag(CF3SO3)(4,7-phen)(CH3CN)]n (1) and [Ag(PO2F2)(4,7-phen)]n (2), were synthesized by the reaction of 4,7-phenanthroline (4,7-phen) and the corresponding AgX salt (X = CF3SO3 - and PF6 -) in 1:2 mole ratio, respectively, in methanol/acetone (1:1 volume ratio) at room temperature. The characterization of the complexes was established on the basis of...
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In: Physical Chemistry Chemical Physics, 2018, vol. 20, no. 17, p. 11692–11701
In a combined experimental and theoretical study we characterize dissociative electron attachment (DEA) to, and electronically excited states of, Fe(CO)5. Both are relevant for electron-induced degradation of Fe(CO)5. The strongest DEA channel is cleavage of one metal–ligand bond that leads to production of Fe(CO)4−. High- resolution spectra of Fe(CO)4− reveal fine structures at the...
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In: Physical Review B, 2018, vol. 97, no. 12, p. 125149
Recent ultrafast magnetic-sensitive measurements [Johnson et al., Phys. Rev. B 92, 184429 (2015); Bothschafter et al., Phys. Rev. B 96, 184414 (2017)] have revealed a delayed melting of the long-range cycloid spin order in TbMnO3 following photoexcitation across the fundamental Mott-Hubbard gap. The microscopic mechanism behind this slow transfer of energy from the photoexcited carriers to...
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In: Integrative Psychological and Behavioral Science, 2013, vol. 47, no. 2, p. 207-219
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In: Monatshefte für Chemie / Chemical Monthly, 2005, vol. 136, no. 6, p. 925-963
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In: Monatshefte für Chemie - Chemical Monthly, 2011, vol. 142, no. 6, p. 593-597
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In: The European Physical Journal B - Condensed Matter and Complex Systems, 2005, vol. 47, no. 2, p. 185-192
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