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Université de Fribourg

Novel iron tweezers complexes for hydrogenation and polymerization of olefins

Mafua, Roger ; Jenny, Titus A. (Dir.)

Thèse de doctorat : Université de Fribourg, 2006 ; no. 1503.

The use of organometallic complexes as catalysts became a very significant topic in the field of material chemistry. However, despite of this development, only few of them contain iron(II), except the tridentate complex diimine pyridine developed by Gibson and Brookhart and employed in the olefin polymerization. Unfortunately, this model suffers by its lack of tolerance towards the minor changes...