Université de Fribourg

Betti bases from 4-(3-pyridazo)-1-naphthol: synthesis, coordination behaviour and unusual substitution reactions

Kurteva, Vanya B. ; Lubenov, Lubomir A. ; Shivachev, Boris L. ; Nikolova, Rositsa P. ; Fromm, Katharina M.

In: ChemistrySelect, 2018, vol. 3, no. 43, p. 12017–12021

A series of Betti bases from 4‐(3‐pyridyl)azo‐1‐naphthol dye, possessing flexible methylene or more constrained aryl‐methyne spaced NH‐containing side‐chains, were obtained and characterized. It was shown by NMR spectroscopy that the ligands exist in keto form. The products’ structure was confirmed by single crystal XRD of a selected sample. A study on the coordination ability...

Université de Fribourg

Switching azonaphthols containing a side chain with limited flexibility. Part 1. Synthesis and tautomeric properties

Kurteva, Vanya B. ; Antonov, Liudmil ; Nedeltcheva, Daniela V. ; Crochet, Aurélien ; Fromm, Katharina M. ; Nikolova, Rositsa P. ; Shivachev, Boris L. ; Nikiforova, Maya S.

In: Dyes and Pigments, 2012, vol. 92, no. 3, p. 1266–1277

A series of azo dyes, possessing amide fragments with restricted flexibility tethered to 4-(phenyldiazenyl)naphthalen-1-ol, was obtained from 1-hydroxy-2-naphthoic acid by subsequent conversion to amides and diazo coupling. It was shown that the position of the tautomeric equilibrium in solution strongly depends on the solvent in both UV and NMR concentration scale. The compounds exist as...

See also: similar author names
1 Nikolova, Rositsa
2 Nikolova, Rositsa P.