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Université de Fribourg

Wavelength-dispersive spectrometer for X-ray microfluorescence analysis at the X-ray microscopy beamline ID21 (ESRF)

Szlachetko, Jakub ; Cotte, M. ; Morse, J. ; Salomé, M. ; Jagodzinski, P. ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Kayser, Yves ; Susini, J.

In: Journal of Synchrotron Radiation, 2010, vol. 17, no. 3, p. 400-408

The development of a wavelength-dispersive spectrometer for microfluorescence analysis at the X-ray Microscopy ID21 beamline of the European Synchrotron Radiation Facility (ESRF) is reported. The spectrometer is based on a polycapillary optic for X-ray fluorescence collection and is operated in a flat-crystal geometry. The design considerations as well as operation characteristics of the...

Université de Fribourg

Single-photon double K-shell ionization of low-Z atoms

Hoszowska, Joanna ; Kheifets, A. S. ; Dousse, Jean-Claude ; Bray, Igor ; Cao, Wei ; Fennane, Karima ; Kayser, Yves ; Kavčič, Matjaz ; Szlachetko, Jakub ; Szlachetko, Monika

In: Journal of Physics: Conference Series, 2010, vol. 212, no. 1, p. 012006

The photon energy dependence of the double K-shell ionization of light atoms is reported. Experimental double-to-single photoionization cross section ratios for Mg, Al, Si and Ca were obtained from measurements of high-resolution x-ray emission spectra. The double photoionization (DPI) cross-sections for K-shell hollow atom production are compared to convergent close-coupling calculations (CCC)...

Université de Fribourg

High-resolution X-ray study of the multiple ionization of Pd atoms by fast oxygen ions

Czarnota, M. ; Banaś, D. ; Berset, Michel ; Chmielewska, D. ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Maillard, Yves-Patrick ; Mauron, Olivier ; Pajek, M. ; Polasik, M. ; Raboud, Pierre-Alexandre ; Rzadkiewicz, J. ; Słabkowska, K. ; Sujkowski, Z.

In: The European Physical Journal D, 2010, p. -

The multiple ionization of the L- and M-shells of Pd by fast oxygen ions has been studied by measuring with high-resolution the satellite structures of the Lα1,2 X-ray transitions. Relativistic multi-configuration Dirac-Fock (MCDF) calculations were used to interpret the complex X-ray spectrum, allowing to derive the number of L- and M-shell spectator vacancies at the moment of the...

Université de Fribourg

Depth profiles of Al impurities implanted in Si wafers determined by means of the high-resolution grazing emission X-ray fluorescence technique

Kayser, Yves ; Banaś, D. ; Cao, Wei ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Jagodziński, P. ; Kavčič, Matjaz ; Kubala-Kukuś, A. ; Nowak, S. ; Pajek, M. ; Szlachetko, Jakub

In: Spectrochimica Acta Part B: Atomic Spectroscopy, 2010, p. -

The synchrotron radiation based high-resolution grazing emission X-ray fluorescence (GEXRF) technique was used to extract the distribution of Al ions implanted with a dose of 10¹⁶ atoms/cm² in Si wafers with energies ranging between 1 and 100 keV. The depth distributions of the implanted ions were deduced from the measured angular profiles of the Al-Kα X-ray fluorescence line with...

Université de Fribourg

Energies and widths of atomic core-levels in liquid mercury

Maillard, Yves-Patrick ; Dousse, Jean-Claude ; Hoszowska, Joanna

In: The European Physical Journal D, 2010, vol. 57, no. 2, p. 155-170

High-resolution measurements of the photoinduced X-ray emission of liquid mercury were performed, using a transmission DuMond-type crystal spectrometer for transitions above 11 keV and a reflection von Hamos-type crystal spectrometer for transitions below 11 keV. The target X-ray fluorescence was produced by irradiating the sample with the Bremsstrahlung from X-ray tubes. The energies and...

Université de Fribourg

The satellites and hypersatellites of Lα1 2 and Lβ1 x-ray transitions in zirconium excited by oxygen and neon ions

Czarnota, M. ; Pajek, M. ; Banaś, D. ; Dousse, Jean-Claude ; Berset, Michel ; Mauron, Olivier ; Maillard, Yves-Patrick ; Raboud, Pierre-Alexandre ; Hoszowska, Joanna ; Polasik, M. ; Słabkowska, K. ; Chmielewska, D. ; Rzadkiewicz, J. ; Sujkowski, Z.

In: Journal of Physics: Conference Series, 2009, vol. 194, p. 152012

The interpretation of L-shell satellites and hypersatellites for Lα1,2 (L₃→M4,5) and Lβ₁ (L₂→M₄) x-ray transitions in zirconium multiply ionized by oxygen and neon ions is reported. The x-ray spectra were measured with a high-resolution von Hamos spectrometer and interpreted in terms the relativistic...

Université de Fribourg

Synchrotron-radiation-based determination of Xe L-subshell Coster-Kronig yields: a reexamination via high-resolution x-ray spectroscopy

Cao, Wei ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Žitnik, M. ; Kavčič, Matjaz ; Bučar, K.

In: Physical Review A, 2010, vol. 81, no. 1, p. 012501

The xenon L-subshell Coster-Kronig (CK) transition yields were revisited via high-resolution measurements of the Lα1,2 (L₃-M4,5) and Lβ₁ (L₂-M₄) x-ray emission lines. The L x-ray spectra were measured employing a Johansson-type curved crystal spectrometer and energy-tunable synchrotron radiation. The CK yields were derived from the relative L x-ray intensity jumps...

Université de Fribourg

Observation of ultralow-level Al impurities on a silicon surface by high-resolution grazing emission x-ray fluorescence excited by synchrotron radiation

Kubala-Kukus, A. ; Banas, D. ; Cao, Wei ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Kayser, Yves ; Pajek, M. ; Salomé, M. ; Susini, J. ; Szlachetko, Jakub ; Szlachetko, Monika

In: Physical Review B, 2009, vol. 11, p. 113305

We demonstrate that ultralow-level Al impurities on a silicon surface can be measured by using the high-resolution grazing emission x-ray fluorescence (GEXRF) technique combined with synchrotron-radiation excitation. An Al-impurity level of about 10¹² atoms/cm² was reached by observing the Al Kα x-ray fluorescence in the resonant Raman-scattering background-“free” regime by...

Université de Fribourg

Crystal optics for hard-X-ray spectroscopy of highly charged ions

Beyer, H.F. ; Attia, D. ; Banas, D. ; Bigot, E.-O. Le ; Bosch, F. ; Dousse, Jean-Claude ; Förster, E. ; Gumberidze, A. ; Hagmann, S. ; Heß, S. ; Hoszowska, Joanna ; Indelicato, P. ; Jagodzinski, P. ; Kozhuharov, Chr. ; Krings, Th. ; Liesen, D. ; Ma, X. ; Manil, B. ; Mohos, I. ; Pajek, M. ; Protić, D. ; Reuschl, R. ; Rzadkiewicz, J. ; Simionovici, A. ; Spillmann, U. ; Stachura, Z. ; Stöhlker, Th. ; Trassinelli, M. ; Trotsenko, S. ; Warczak, A. ; Wehrhan, O. ; Ziegler, E.

In: Spectrochimica Acta Part B: Atomic Spectroscopy, 2009, vol. 64, no. 8, p. 736-743

A twin crystal-spectrometer assembly, operated in the focusing compensated asymmetric Laue geometry has been developed for accurate spectroscopy of fast highly charged heavy ions in the hard-X-ray region. Coupled to the focusing crystal optics is a specially developed two-dimensional position-sensitive X-ray detector which is necessary for retaining spectral resolution also for fast moving...