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Accounting for effective interactions among charged microgels

Aguirre-Manzo, L. A. ; Ledesma-Motolinía, Mónica ; Rojas-Ochoa, Luis Fernando ; Trappe, Véronique ; Callejas-Fernández, J. ; Haro-Pérez, Catalina ; González-Mozuelos, P.

In: Physical Review E, 2019, vol. 100, no. 3, p. 032602

We introduce a theoretical approach to describe structural correlations among charged permeable spheres at finite particle concentrations. This theory explicitly accounts for correlations among microions and between microions and macroions and allows for the proposal of an effective interaction among macroions that successfully captures structural correlations observed in poly- N -isopropyl...