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Université de Fribourg

Cis-Dioxido-molybdenum(VI) complexes of tridentate ONO hydrazone Schiff base: Synthesis, characterization, X-ray crystal structure, DFT calculation and catalytic activity

Ebrahimipour, S. Yousef ; Khabazadeh, , , Hojatollah ; Castro, Jesús ; Sheikhshoaie, Iran ; Crochet, Aurélien ; Fromm, Katharina M.

In: Inorganica Chimica Acta, 2015, vol. 427, p. 52–61

Two new cis-MoO₂ [MoO₂(L)(EtOH)] (1), [MoO₂(L) (Py)] (2) [L: (3-methoxy-2oxidobenzylidene)benzohydrazidato], complexes have been synthesized and fully characterized on the basis of elemental analysis, FT-IR, molar conductivity, ¹H NMR, ¹³C NMR and electronic spectra. The structure of complexes has been accomplished by single crystal X-ray...