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Université de Fribourg

Stock fluctuations are correlated and amplified across networks of interlocking directorates

Saavedra, Serguei ; Gilarranz, Luis J ; Rohr, Rudolf P. ; Schnabel, Michael ; Uzzi, Brian ; Bascompte, Jordi

In: EPJ Data Science, 2014, vol. 3, no. 1, p. 30

Traded corporations are required by law to have a majority of outside directors on their board. This requirement allows the existence of directors who sit on the board of two or more corporations at the same time, generating what is commonly known as interlocking directorates. While research has shown that networks of interlocking directorates facilitate the transmission of information between...

Université de Fribourg

Resonance effects in elastic cross sections for electron scattering on pyrimidine: Experiment and theory

Regeta, Khrystyna ; Allan, Michael ; Winstead, Carl ; McKoy, Vincent ; Mašín, Zdeněk ; Gorfinkiel, Jimena D.

In: The Journal of Chemical Physics, 2016, vol. 144, no. 2, p. 024301

We measured differential cross sections for elastic (rotationally integrated) electron scattering on pyrimidine, both as a function of angle up to 180∘ at electron energies of 1, 5, 10, and 20 eV and as a function of electron energy in the range 0.1–14 eV. The experimental results are compared to the results of the fixed-nuclei Schwinger variational and R-matrix theoretical methods, which...

Université de Fribourg

Absolute cross sections for electronic excitation of pyrimidine by electron impact

Regeta, Khrystyna ; Allan, Michael ; Mašín, Zdeněk ; Gorfinkiel, Jimena D.

In: The Journal of Chemical Physics, 2016, vol. 144, no. 2, p. 024302

We measured differential cross sections for electron-impact electronic excitation of pyrimidine, both as a function of electron energy up to 18 eV, and of scattering angle up to 180°. The emphasis of the present work is on recording detailed excitation functions revealing resonances in the excitation process. The differential cross sections were summed to obtain integral cross sections. These...

Université de Fribourg

Toxicity and protective effects of cerium oxide nanoparticles (Nanoceria) depending on their preparation method, particle size, cell type, and exposure route

Gagnon, Jacinthe ; Fromm, Katharina M.

In: European Journal of Inorganic Chemistry, 2015, vol. 2015, no. 27, p. 4510–4517

Nanoceria (cerium oxide nanoparticles) toxicity is currently a concern because of its use in motor vehicles in order to reduce carbon monoxide (CO), nitrogen oxides (NOx), and hydrocarbons in exhaust gases. In addition, many questions arise with respect to its biomedical applications exploiting its potential to protect cells against irradiation and oxidative stress. Indeed, toxicology studies on...

Université de Fribourg

Toward large tubular helices based on the polymerization of tri(benzamide)s

Schulze, Maren ; Kilbinger, Andreas F. M.

In: Journal of Polymer Science Part A: Polymer Chemistry, 2016, p. -

Herein we present the synthesis and polycondensation of mono- and di-N-protected, bis-substituted tri(benzamide)s with the aim to create large, tubular helices. We synthesized 2,4-dimethoxy and 2,5-bis-TEGylated aminobenzoic acid derivatives as bent and linear monomers and introduced p-methoxybenzyl (PMB) amide protecting groups to the oligobenzamide backbone. An iterative coupling strategy...

Université de Fribourg

Construction of polynuclear lanthanide (Ln = DyIII, TbIII, and NdIII) cage complexes using pyridine–pyrazole-based ligands: versatile molecular topologies and SMM behavior

Bala, Sukhen ; Bishwas, Mousumi Sen ; Pramanik, Bhaskar ; Khanra, Sumit ; Fromm, Katharina M. ; Poddar, Pankaj ; Mondal, Raju

In: Inorganic Chemistry, 2015, vol. 54, no. 17, p. 8197–8206

Employment of two different pyridyl–pyrazolyl-based ligands afforded three octanuclear lanthanide(III) (Ln = Dy, Tb) cage compounds and one hexanuclear neodymium(III) coordination cage, exhibiting versatile molecular architectures including a butterfly core. Relatively less common semirigid pyridyl–pyrazolyl-based asymmetric ligand systems show an interesting trend of forming polynuclear...

Université de Fribourg

Ultrathin ceramic membranes as scaffolds for functional cell coculture models on a biomimetic scale

Jud, Corinne ; Ahmed, Sher ; Müller, Loretta ; Kinnear, Calum ; Vanhecke, Dimitri ; Umehara, Yuki ; Frey, Sabine ; Liley, Martha ; Angeloni, Silvia ; Petri-Fink, Alke ; Rothen-Rutishauser, Barbara

In: BioResearch Open Access, 2015, vol. 4, no. 1, p. 457–468

Epithelial tissue serves as an interface between biological compartments. Many in vitro epithelial cell models have been developed as an alternative to animal experiments to answer a range of research questions. These in vitro models are grown on permeable two-chamber systems; however, commercially available, polymer-based cell culture inserts are around 10 μm thick. Since the basement...

Université de Fribourg

Prospecting lighting applications with ligand field tools and density functional theory: a first-principles account of the 4f⁷–4f⁶5d¹ Luminescence of CsMgBr₃:Eu²⁺

Ramanantoanina, Harry ; Cimpoesu, Fanica ; Göttel, Christian ; Sahnoun, Mohammed ; Herden, Benjamin ; Suta, Markus ; Wickleder, Claudia ; Urland, Werner ; Daul, Claude

In: Inorganic Chemistry, 2015, vol. 54, no. 17, p. 8319–8326

The most efficient way to provide domestic lighting nowadays is by light-emitting diodes (LEDs) technology combined with phosphors shifting the blue and UV emission toward a desirable sunlight spectrum. A route in the quest for warm-white light goes toward the discovery and tuning of the lanthanide-based phosphors, a difficult task, in experimental and technical respects. A proper theoretical...

Université de Fribourg

Synthesis of FMRFaNV, a photoreleasable caged transmitter designed to study neuron–glia interactions in the central nervous System

Janett, Elia ; Bernardinelli, Yann ; Müller, Dominique ; Bochet, Christian G.

In: Bioconjugate Chemistry, 2015, vol. 26, no. 12, p. 2408–2418

Neuroscience studies require technologies able to deliver compounds with both scale and timing compatibility with morphological and physiological synaptic properties. In this light, two-photon flash photolysis has been extensively used to successfully apply glutamate or other neurotransmitters at the synaptic level. However, the set of commercially available caged compounds is restricted and...

Université de Fribourg

Charge transfer dynamics from organometal halide perovskite to polymeric hole transport materials in hybrid solar cells

Brauer, Jan C. ; Lee, Yong Hui ; Nazeeruddin, Mohammad Khaja ; Banerji, Natalie

In: The Journal of Physical Chemistry Letters, 2015, vol. 6, no. 18, p. 3675–3681

Organometal halide perovskites have emerged as promising next-generation solar cell technologies presenting outstanding efficiencies. However, many questions concerning their working principles remain to be answered. Here, we present a detailed study of hole transfer dynamics into polymeric hole transporting materials (HTMs), poly(triarylamine) (PTAA), poly(3-hexylthiophee-2,5-diyl (P3HT), and...