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Université de Neuchâtel

Hydrogen-bonded metalla-assemblies

Zhang, Fan ; Therrien, Bruno (Dir.)

Thèse de doctorat : Université de Neuchâtel, 2018.

Hydrogen bonds are the most utilized non-covalent interactions in biological systems, due to their directionality, stability, reversibility and diversity. The weak strength of hydrogen-bond can be modified by combining several hydrogen bonds in the same unit, like in the melamine∙cyanuric/barbituric acid rosette-type system. Arene ruthenium metalla-assemblies have showed a great biological...

Université de Neuchâtel

Synthesis, characterization and exploration of the catalytic, supramolecular and biological applications of dinuclear complexes

Johnpeter, Justin Paul Raj ; Therrien, Bruno (Dir.)

Thèse de doctorat : Université de Neuchâtel, 2013.

The work presented in this thesis involves the synthesis and characterization of dinuclear ruthenium, rhodium and iridium complexes. The catalytic, supramolecular and biological applications of these dinuclear complexes will be discussed. In the first part, the synthesis of sawhorse-type diruthenium tetracarbonyl complexes and their catalytic applications in the supercritical carbon dioxide...

Université de Neuchâtel

Thiolato-Bridged Arene–Ruthenium Complexes: Synthesis, Molecular Structure, Reactivity, and Anticancer Activity of the Dinuclear Complexes [(arene)2Ru2 (SR)2Cl2]

Ibao, Anne-Flore ; Gras, Michaël ; Therrien, Bruno ; Süss-Fink, Georg ; Zava, Olivier ; Dyson, Paul J.

In: European Journal of Inorganic Chemistry, 2012, vol. 2012, no. 9, p. 1531-1535

Treatment of an arene–ruthenium dichloride dimer with thiols RSH to lead to cationic trithiolato complexes of the type [(arene) 2Ru2(SR)3]+ was shown to proceed through the neutral thiolato complexes [(arene)2Ru2(SR)2Cl2], which have been isolated and characterized for arene =...

Université de Neuchâtel

Ru2(CO)4(OOCR)2L2 sawhorse-type complexes containing axial 5-(4-pyridyl)-10,15,20-triphenylporphyrin ligands

Gras, Michaël ; Barry, Nicolas P.E. ; Therrien, Bruno ; Süss-Fink, Georg

In: Inorganica Chimica Acta, 2011, vol. 371, no. 1, p. 59-62

The thermal reaction of Ru3(CO)12 with various carboxylic acids (benzoic, 4-hydroxyphenylacetic, ferrocenic, stearic, oleic, 4-(octadecyloxy)benzoic) in refluxing tetrahydrofuran, followed by addition of 5-(4-pyridyl)-10,15,20-triphenylporphyrin (L), gives the dinuclear complexes Ru2(CO)4(OOCR)2L2 (1: R =...