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Reactivity of hexanuclear ruthenium metallaprisms towards nucleotides and a DNA decamer

Paul, Lydia ; Therrien, Bruno ; Furrer, Julien

In: JBIC Journal of Biological Inorganic Chemistry, 2015, vol. 20, no. 1, p. 49-59

Synthesis and reactivity of the 17 e- complex [Re(II)Br4(CO)2]2 : A convenient entry into rhenium(II) chemistry

Zobi, Fabio ; Kromer, Lukas ; Spingler, Bernhard ; Alberto, Roger

In: Inorganic Chemistry, 2009, vol. 48, no. 18, p. 8965-8970

The reduction of (Et(4)N)[Re(III)Br(4)(CO)(2)] (1) by 0.5 equiv of tetrakis- dimethylaminoethylene in acetonitrile yields directly the air-stable, 17-electron Re(II) synthon (Et(4)N)(2)[Re(II)Br(4)(CO)(2)] (2) in nearly quantitative yield. The versatility of 2 as a synthon for Re(II) chemistry was demonstrated by substitution reactions of [Re(II)Br(4)(CO)(2)](2-) with different mono-, bi-,...

Hydrogen-bonded metalla-assemblies

Zhang, Fan ; Therrien, Bruno (Dir.)

Thèse de doctorat : Université de Neuchâtel, 2018.

Hydrogen bonds are the most utilized non-covalent interactions in biological systems, due to their directionality, stability, reversibility and diversity. The weak strength of hydrogen-bond can be modified by combining several hydrogen bonds in the same unit, like in the melamine∙cyanuric/barbituric acid rosette-type system. Arene ruthenium metalla-assemblies have showed a great biological...

Hydrogen storage and delivery: immobilization of a highly active homogeneous catalyst for the decomposition of formic acid to hydrogen and carbon dioxide

Gan, Weijia ; Dyson, Paul ; Laurenczy, Gábor

In: Reaction Kinetics and Catalysis Letters, 2009, vol. 98, no. 2, p. 205-213

Sawhorse-type diruthenium tetracarbonyl complexes containing porphyrin-derived ligands as highly selective photosensitizers for female reproductive cancer cells

Schmitt, Frédéric ; Auzias, Mathieu ; Štěpnička, Petr ; Sei, Yoshihisa ; Yamaguchi, Kentaro ; Süss-Fink, Georg ; Therrien, Bruno ; Juillerat-Jeanneret, Lucienne

In: JBIC Journal of Biological Inorganic Chemistry, 2009, vol. 14, no. 5, p. 693-701

Highly cytotoxic trithiophenolatodiruthenium complexes of the type [(η6- p -MeC6H4Pr i )2Ru2(SC6H4- p -X)3]+: synthesis, molecular structure, electrochemistry, cytotoxicity, and glutathione oxidation potential

Giannini, Federico ; Furrer, Julien ; Ibao, Anne-Flore ; Süss-Fink, Georg ; Therrien, Bruno ; Zava, Olivier ; Baquie, Mathurin ; Dyson, Paul ; Štěpnička, Petr

In: JBIC Journal of Biological Inorganic Chemistry, 2012, vol. 17, no. 6, p. 951-960

Combined arene ruthenium porphyrins as chemotherapeutics and photosensitizers for cancer therapy

Schmitt, Frédéric ; Govindaswamy, Padavattan ; Zava, Olivier ; Süss-Fink, Georg ; Juillerat-Jeanneret, Lucienne ; Therrien, Bruno

In: JBIC Journal of Biological Inorganic Chemistry, 2009, vol. 14, no. 1, p. 101-109

Ruthenium versus platinum: interactions of anticancer metallodrugs with duplex oligonucleotides characterised by electrospray ionisation mass spectrometry

Groessl, Michael ; Tsybin, Yury ; Hartinger, Christian ; Keppler, Bernhard ; Dyson, Paul

In: JBIC Journal of Biological Inorganic Chemistry, 2010, vol. 15, no. 5, p. 677-688

Interaction of a ruthenium hexacationic prism with amino acids and biological ligands: ESI mass spectrometry and NMR characterisation of the reaction products

Paul, Lydia ; Therrien, Bruno ; Furrer, Julien

In: JBIC Journal of Biological Inorganic Chemistry, 2012, vol. 17, no. 7, p. 1053-1062

Synthesis, characterization and exploration of the catalytic, supramolecular and biological applications of dinuclear complexes

Johnpeter, Justin Paul Raj ; Therrien, Bruno (Dir.)

Thèse de doctorat : Université de Neuchâtel, 2013.

The work presented in this thesis involves the synthesis and characterization of dinuclear ruthenium, rhodium and iridium complexes. The catalytic, supramolecular and biological applications of these dinuclear complexes will be discussed. In the first part, the synthesis of sawhorse-type diruthenium tetracarbonyl complexes and their catalytic applications in the supercritical carbon dioxide...