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Université de Fribourg

Dehydriding and rehydriding reactions of LiBH₄

Orimo, S. ; Nakamori, Y. ; Kitahara, G. ; Miwa, K. ; Ohba, N. ; Towata, S. ; Züttel, Andreas

In: Journal of Alloys and Compounds, 2005, vol. 404-406, p. 427-430

Structural differences in LiBH₄ before and after the melting reaction at approximately 550 K were investigated to clarify the experimental method for the confirmation of reversible dehydriding and rehydriding reactions. Since the long-range order of LiBH₄ begins to disappear after the melting reaction was achieved, investigation of the atomistic vibrations of the [BH₄]-anion in LiBH₄ was...