Université de Neuchâtel

Shape- and Size-Selective Preparation of Hectorite-Supported Ruthenium Nanoparticles for the Catalytic Hydrogenation of Benzene

Süss-Fink, Georg ; Khan, Farooq-Ahmad ; Boudon, Julien ; Spassov, Vladislav

In: Journal of Cluster Science, 2009, vol. 20, no. 2, p. 341-353

The cationic organometallic aqua complexes formed by hydrolysis of [(C6H6)2RuCl2]2 in water, mainly [(C6H6)Ru(H2O)3]2+, intercalate into white sodium hectorite, replacing the sodium cations between the anionic silicate layers. The yellow hectorite thus obtained reacts in water with...