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    Université de Neuchâtel

    Complexes di-, tri- et tétranucléaires de ruthénium contenant des ligands phosphorés stériquement encombrants pour l'hydroformylation catalytique d'oléfines

    Lozano Diz, Enrique ; Süss-Fink, Georg (Dir.)

    Thèse de doctorat : Université de Neuchâtel : 2002 ; 1664.

    In this thesis new di-, tri- and tetranuclear ruthenium clusters containing mono- and diphosphine ligands have been studied: synthesis, structure and catalytic potential for olefin hydroformylation. The first part of this thesis is devoted to the synthesis, spectroscopic and X-ray structure analysis of trinuclear ruthenium complexes containing the bulky diphosphine ligands F-dppe and dcpm. In...